Trichloro(4,4′-dimethyl-2,2′-bipyridine-N,N′)manganese(III) acetonitrile solvate(1/1)

被引：0
|
作者：
Abboud, KA [1 ]
Ward, BH [1 ]
Talham, DR [1 ]
机构：
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷
关键词：
D O I：
10.1107/S0108270197012419
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structure of the title compound, [MnCl3(C12H12-N-2)]. CH3CN, consists of monomeric manganese(III) species with distorted trigonal bipyramidal geometry; Mn-N-ax 2.035 (1), Mn-N-eq 2.096 (1), Mn-Cl-ax 2.2187(5), and Mn-Cl-eq 2.2587(5) and 2.3117 (5) Angstrom. The Mn complexes stack as pairs in columns along the a axis, separated by columns of acetonitrile. Spacing between the Mn-III atoms is not uniform and alternating distances of 6.704(1) (-x, -y, -z) and 7.713 (1) Angstrom (1-x, -y, -z) are observed.
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页码：180 / 181
页数：2
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