Selective oxidation of glycerol catalyzed by iron complexes

被引：55

作者：

Crotti, Corrado ^{[1
]}

Farnetti, Erica ^{[2
]}

机构：

[1] CNR, Ist Struttura Mat, Unita Operat Support Trieste, I-34149 Trieste, Italy

[2] Univ Trieste, Dipartimento Sci Chim & Farmaceut, I-34127 Trieste, Italy

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2015年 / 396卷

关键词：

Iron catalysts; Glycerol valorization; Selective oxidation; Dihydroxyacetone; FORMIC-ACID; TRANSFER HYDROGENATION; PRIMARY ALCOHOLS; REDUCTION; CONVERSION; H2O2; EPOXIDATION; KETONES;

D O I：

10.1016/j.molcata.2014.10.021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Iron complexes with the polydentate ligand bis(2-pyridinylmethyl)amine (BPA) were employed as catalysts for the oxidation of glycerol using hydrogen peroxide as oxidant. The only observed reaction products were dihydroxyacetone (DHA) and formic acid. Although the overall conversion was in all cases lower than 50%, by accurate choice of the experimental conditions selectivities in DHA up to 100% were obtained. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：353 / 359

页数：7

共 63 条

[1] Solvent free oxidation of primary alcohols and diols using thymine iron(III) catalyst [J].

Al-Hunaiti, Afnan ;

Niemi, Teemu ;

Sibaouih, Ahlam ;

Pihko, Petri ;

Leskela, Markku ;

Repo, Timo .

CHEMICAL COMMUNICATIONS, 2010, 46 (48) :9250-9252

[2] Green Chemistry: Principles and Practice [J].

Anastas, Paul ;

Eghbali, Nicolas .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :301-312

[3] Origins, current status, and future challenges of green chemistry [J].

Anastas, PT ;

Kirchhoff, MM .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694

[4] Alternative Energy Input for Transfer Hydrogenation using Iridium NHC Based Catalysts in Glycerol as Hydrogen Donor and Solvent [J].

Azua, Arturo ;

Mata, Jose A. ;

Peris, Eduardo ;

Lamaty, Frederic ;

Martinez, Jean ;

Colacino, Evelina .

ORGANOMETALLICS, 2012, 31 (10) :3911-3919

[5] Catalytic oxidation of alcohols to carbonyl compounds with hydrogen peroxide using dinuclear iron complexes [J].

Balogh-Hergovich, É ;

Speier, G .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 230 (1-2) :79-83

[6] Improved utilisation of renewable resources: New important derivatives of glycerol [J].

Behr, Arno ;

Eilting, Jens ;

Irawadi, Ken ;

Leschinski, Julia ;

Lindner, Falk .

GREEN CHEMISTRY, 2008, 10 (01) :13-30

[7] Carbon-carbon bond fission on oxidation of primary alcohols to carboxylic acids [J].

Bekish, Andrei V. .

TETRAHEDRON LETTERS, 2012, 53 (24) :3082-3085

[8] Conversion of Biomass into Chemicals over Metal Catalysts [J].

Besson, Michele ;

Gallezot, Pierre ;

Pinel, Catherine .

CHEMICAL REVIEWS, 2014, 114 (03) :1827-1870

[9] CHEMOSELECTIVE HYDROGEN-TRANSFER REDUCTION OF ALPHA,BETA-UNSATURATED KETONES CATALYZED BY ISOSTRUCTURAL IRON(II), RUTHENIUM(II), AND OSMIUM(II) CIS HYDRIDE ETA(2)-DIHYDROGEN COMPLEXES [J].

BIANCHINI, C ;

FARNETTI, E ;

GRAZIANI, M ;

PERUZZINI, M ;

POLO, A .

ORGANOMETALLICS, 1993, 12 (09) :3753-3761

[10] Efficient and Selective Oxidation of Primary and Secondary Alcohols Using an Iron(III)/Phenanthroline Complex: Structural Studies and Catalytic Activity [J].

Biswas, Bhaskar ;

Al-Hunaiti, Afnan ;

Raisanen, Minna T. ;

Ansaloni, Simone ;

Leskela, Markku ;

Repo, Timo ;

Chen, Yen-Tung ;

Tsai, Hui-Lien ;

Naik, Anil D. ;

Railliet, Antoine P. ;

Garcia, Yann ;

Ghosh, Rajarshi ;

Kole, Niranjan .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (28) :4479-4485

← 1 2 3 4 5 6 7 →