Selective oxidation of glycerol catalyzed by iron complexes

被引：50
作者：
Crotti, Corrado [1 ]
Farnetti, Erica [2 ]
机构：
[1] CNR, Ist Struttura Mat, Unita Operat Support Trieste, I-34149 Trieste, Italy
[2] Univ Trieste, Dipartimento Sci Chim & Farmaceut, I-34127 Trieste, Italy
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2015年 / 396卷
关键词：
Iron catalysts; Glycerol valorization; Selective oxidation; Dihydroxyacetone; FORMIC-ACID; TRANSFER HYDROGENATION; PRIMARY ALCOHOLS; REDUCTION; CONVERSION; H2O2; EPOXIDATION; KETONES;
D O I：
10.1016/j.molcata.2014.10.021
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Iron complexes with the polydentate ligand bis(2-pyridinylmethyl)amine (BPA) were employed as catalysts for the oxidation of glycerol using hydrogen peroxide as oxidant. The only observed reaction products were dihydroxyacetone (DHA) and formic acid. Although the overall conversion was in all cases lower than 50%, by accurate choice of the experimental conditions selectivities in DHA up to 100% were obtained. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：353 / 359
页数：7
相关论文
共 63 条
  • [1] Solvent free oxidation of primary alcohols and diols using thymine iron(III) catalyst
    Al-Hunaiti, Afnan
    Niemi, Teemu
    Sibaouih, Ahlam
    Pihko, Petri
    Leskela, Markku
    Repo, Timo
    [J]. CHEMICAL COMMUNICATIONS, 2010, 46 (48) : 9250 - 9252
  • [2] Green Chemistry: Principles and Practice
    Anastas, Paul
    Eghbali, Nicolas
    [J]. CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) : 301 - 312
  • [3] Origins, current status, and future challenges of green chemistry
    Anastas, PT
    Kirchhoff, MM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) : 686 - 694
  • [4] Alternative Energy Input for Transfer Hydrogenation using Iridium NHC Based Catalysts in Glycerol as Hydrogen Donor and Solvent
    Azua, Arturo
    Mata, Jose A.
    Peris, Eduardo
    Lamaty, Frederic
    Martinez, Jean
    Colacino, Evelina
    [J]. ORGANOMETALLICS, 2012, 31 (10) : 3911 - 3919
  • [5] Catalytic oxidation of alcohols to carbonyl compounds with hydrogen peroxide using dinuclear iron complexes
    Balogh-Hergovich, É
    Speier, G
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 230 (1-2) : 79 - 83
  • [6] Improved utilisation of renewable resources: New important derivatives of glycerol
    Behr, Arno
    Eilting, Jens
    Irawadi, Ken
    Leschinski, Julia
    Lindner, Falk
    [J]. GREEN CHEMISTRY, 2008, 10 (01) : 13 - 30
  • [7] Carbon-carbon bond fission on oxidation of primary alcohols to carboxylic acids
    Bekish, Andrei V.
    [J]. TETRAHEDRON LETTERS, 2012, 53 (24) : 3082 - 3085
  • [8] Conversion of Biomass into Chemicals over Metal Catalysts
    Besson, Michele
    Gallezot, Pierre
    Pinel, Catherine
    [J]. CHEMICAL REVIEWS, 2014, 114 (03) : 1827 - 1870
  • [9] CHEMOSELECTIVE HYDROGEN-TRANSFER REDUCTION OF ALPHA,BETA-UNSATURATED KETONES CATALYZED BY ISOSTRUCTURAL IRON(II), RUTHENIUM(II), AND OSMIUM(II) CIS HYDRIDE ETA(2)-DIHYDROGEN COMPLEXES
    BIANCHINI, C
    FARNETTI, E
    GRAZIANI, M
    PERUZZINI, M
    POLO, A
    [J]. ORGANOMETALLICS, 1993, 12 (09) : 3753 - 3761
  • [10] Efficient and Selective Oxidation of Primary and Secondary Alcohols Using an Iron(III)/Phenanthroline Complex: Structural Studies and Catalytic Activity
    Biswas, Bhaskar
    Al-Hunaiti, Afnan
    Raisanen, Minna T.
    Ansaloni, Simone
    Leskela, Markku
    Repo, Timo
    Chen, Yen-Tung
    Tsai, Hui-Lien
    Naik, Anil D.
    Railliet, Antoine P.
    Garcia, Yann
    Ghosh, Rajarshi
    Kole, Niranjan
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (28) : 4479 - 4485
1234567