Retention of chirality in electron-induced reactions

被引：0
作者：
Cheng, Fang [1 ,2 ,5 ]
Leung, Lydie [1 ,2 ]
Wang, Chen-Guang [1 ,2 ,3 ,4 ]
Ji, Wei [3 ,4 ]
Polanyi, John C. [1 ,2 ]
机构：
[1] Univ Toronto, Dept Chem, Lash Miller Chem Labs, 80 St George St, Toronto, ON M5S 3H6, Canada
[2] Univ Toronto, Inst Opt Sci, 80 St George St, Toronto, ON M5S 3H6, Canada
[3] Renmin Univ China, Dept Phys, Beijing 100872, Peoples R China
[4] Renmin Univ China, Beijing Key Lab Optoelect Funct Mat & Micronano D, Beijing 100872, Peoples R China
[5] Natl Univ Singapore, Ctr Adv Mat 2D, 1 Create Way,Create Tower, Singapore 138602, Singapore
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 36期
基金：
加拿大自然科学与工程研究理事会; 中国国家自然科学基金; 加拿大创新基金会;
关键词：
LOCALIZED ATOMIC REACTION; CHARGE DELOCALIZATION; METAL-SURFACE; REACTION LAR; SI(111) 7X7; MOLECULES; CU(110); 1,4-DIBROMOBENZENE; DISSOCIATION; HALOGENATION;
D O I：
10.1039/c6cc00849f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two enantiomers were observed by Scanning Tunneling Microscopy (STM) when meta-iodopyridine was physisorbed on a 4.6 K Cu(110) surface. The chirality of the reagent was retained in the products of the electron-induced reaction. Dynamical calculations showed this to be a consequence of the reaction occurring on one side of the mirror plane.
引用
收藏
页码：6115 / 6118
页数：4
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