Syntheses of functionalized 2,2′:6′,2′′-terpyridines

被引:174
作者
Heller, M
Schubert, US
机构
[1] Univ Munich, Ctr NanoSci, D-80799 Munich, Germany
[2] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
关键词
nitrogen heterocycles; terpyridines; synthetic strategies;
D O I
10.1002/ejoc.200390150
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
2,2':6',2''-Terpyridine compounds are important chelating ligands in a multitude of applications in the fields of supramolecular and macromolecular chemistry as well as electrochemistry. Therefore, a "pool" of functionalized terpyridine derivatives is essential. Classical and modern synthetic strategies towards terpyridine systems and novel functional 2,2':6',2"-terpyridine compounds that originated in the last seven years are reviewed comprehensively.
引用
收藏
页码:947 / 961
页数:15
相关论文
共 148 条
[1]   A new approach to symmetric 2,2′:6′,2"-terpyridines [J].
Adrian, JC ;
Hassib, L ;
De Kimpe, N ;
Keppens, M .
TETRAHEDRON, 1998, 54 (11) :2365-2370
[2]  
[Anonymous], 2002, ANGEW CHEM, V114, P3016, DOI DOI 10.1002/1521-3757(20020816)114:16<3016::AID-ANGE3016>3.0.CO
[3]  
2-5
[4]   Carbaborane-functionalised 2,2′:6′,2"-terpyridine ligands for metallosupramolecular chemistry:: Syntheses, complex formation, and the crystal and molecular structures of 4′-(optho-carboranyl)-2,2′:6′,2"-terpyridine and 4′-(ortho-carboranylpropoxy)-2,2′:6′,2"-terpyridine [J].
Armspach, D ;
Constable, EC ;
Housecroft, CE ;
Neuburger, M ;
Zehnder, M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) :193-206
[5]   Palladium-catalysed cross-coupling reactions of ruthenium bis-terpyridyl complexes: strategies for the incorporation and exploitation of boronic acid functionality [J].
Aspley, CJ ;
Williams, JAG .
NEW JOURNAL OF CHEMISTRY, 2001, 25 (09) :1136-1147
[6]   Building off the back of chelators: Synthesis of 3,3''-bis(4-methylphenyl)-2,2':6',2''-terpyridine [J].
Benniston, AC .
TETRAHEDRON LETTERS, 1997, 38 (47) :8279-8282
[7]   Properties and single-crystal X-ray structure of bis[3,3"-bis(4-methylphenyl)-2,2′:6′,2"-terpyridine]iron(II) hexafluorophosphate acetonitrile diisopropyl ether (1/1.5/1) [J].
Benniston, AC ;
Farrugia, LJ ;
Mackie, PR ;
Mallinson, P ;
Clegg, W ;
Teat, SJ .
AUSTRALIAN JOURNAL OF CHEMISTRY, 2000, 53 (08) :707-713
[8]  
BILLANCIA G, 2001, POLYM MAT SCI ENG, V85, P508
[9]   Stepwise synthetic strategy for the preparation of trinuclear complexes of bis(terpyridyl) bridging ligands containing aza-crown macrocyclic spacer groups [J].
Bushell, KL ;
Couchman, SM ;
Jeffery, JC ;
Rees, LH ;
Ward, MD .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (20) :3397-3403
[10]  
Cardenas DJ, 1996, SYNLETT, P916