Structural and magnetic properties of (Nd1-xHox)3Fe27.31Ti1.69 compounds

被引:4
作者
Wang, WQ [1 ]
Wang, JL
Yan, Y
Du, XB
Wang, XF
Jin, HM
机构
[1] Jilin Univ, Dept Phys, Changchun 130023, Peoples R China
[2] Chinese Acad Sci, Inst Phys, State Key Lab Magnetism, Beijing 100080, Peoples R China
[3] Jilin Univ, State Key Lab Superhard Mat, Changchun 130023, Peoples R China
关键词
rare earth compounds; transition metal compounds; anisotropy; magnetic measurements;
D O I
10.1016/S0925-8388(02)00905-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Structural and magnetic properties of the (Nd1-xHox)(3)Fe27.31Ti1.69 compounds have been investigated by means of X-ray diffraction and magnetic measurements. All the compounds with xless than or equal to0.6 crystallize in the Nd-3(Fe,Ti)(29)-type structure. Substitution of Ho for Nd leads to a contraction of the unit-cell volume and a monotonic decrease of the saturation moments M-s at 5 K. As the temperature decreases from room temperature to 5 K, a spin reorientation from easy plane to the easy cone occurs for all (Nd1-xHox)(3)Fe27.31Ti1.69 compounds investigated. It has been found that the Curie temperature T-c of the (Nd1-xHox)(3)Fe27.31Ti1.69 compound almost has a constant value, whereas the spin reorientation temperature, T-sr, decreases with increasing x. The anisotropy fields, B-a, at room temperature for the (Nd1-xHox)(3)Fe27.31Ti1.69 compounds have been determined by the singular point detection method and are found to be almost independent of the Ho content. A tentative spin phase diagram has been constructed for the (Nd1-xHox)(3)Fe27.31Ti1.69 compounds. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:23 / 27
页数:5
相关论文
共 17 条
[1]   NONANALITICITY OF MAGNETIZATION CURVE - APPLICATION TO MEASUREMENT OF ANISOTROPY IN POLYCRYSTALLINE SAMPLES [J].
ASTI, G ;
RINALDI, S .
PHYSICAL REVIEW LETTERS, 1972, 28 (24) :1584-&
[2]   NEW RARE-EARTH INTERMETALLIC PHASES R(3)(FE,M)(29)X(N) - (R=CE, PR, ND, SM, GD, M=TI, V, CR, MN, AND X=H, N, C) [J].
CADOGAN, JM ;
LI, HS ;
MARGARIAN, A ;
DUNLOP, JB ;
RYAN, DH ;
COLLOCOTT, SJ ;
DAVIS, RL .
JOURNAL OF APPLIED PHYSICS, 1994, 76 (10) :6138-6143
[3]  
COLLOCOTT SJ, 1992, UNPUB P 7 INT S MAGN, P437
[4]   Determination of the easy magnetisation direction by X-ray diffraction analysis at room temperature in the R(3)(Fe, M)(29) compounds: R=Pr, Nd, Sm, Gd, Tb, Dy and Y; M=Ti and V [J].
Courtois, D ;
Li, HS ;
Cadogan, JM .
SOLID STATE COMMUNICATIONS, 1996, 98 (06) :565-570
[5]  
FRANSE JJM, 1993, HDB MAGNETIC MAT, V7, P307, DOI DOI 10.1016/S1567-2719(05)80046-0
[6]   Syntheses and magnetic properties of Tb3Fe29-xCrx compounds [J].
Han, XF ;
Pan, HG ;
Liu, HL ;
Yang, FM ;
Zheng, YW .
PHYSICAL REVIEW B, 1997, 56 (14) :8867-8875
[7]   Phase diagram and compounds of the Gd-Fe-Nb ternary alloy system in the Fe-rich corner [J].
Huang, F ;
Liang, JK ;
Liu, QL ;
Chen, XL ;
Huo, GY .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (40) :9183-9188
[8]   EXISTENCE RANGE, STRUCTURAL AND MAGNETIC-PROPERTIES OF ND-3 FE27.5TI1.5-YMOY AND ND3FE27.5TI1.5-YMOYNX (0.0-LESS-THAN-OR-EQUAL-TO-Y-LESS-THAN-OR-EQUAL-TO-1.5) [J].
KALOGIROU, O ;
PSYCHARIS, V ;
SAETTAS, L ;
NIARCHOS, D .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1995, 146 (03) :335-345
[9]   Magnetocrystalline anisotropy of non-uniaxial R-T magnetic materials studied by the singular point detection technique: An application to R(2)Fe(17-x)Ga(x) compounds (R=Y or Gd and x=0 or 1) [J].
Kou, XC ;
Sinnecker, EHCP ;
Grossinger, R .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1996, 8 (10) :1557-1565
[10]   MOSSBAUER STUDY OF A NOVEL SERIES OF TERNARY RARE-EARTH IRON-RICH INTERMETALLICS - ND(FE1-XTIX)(6+Y) (X-APPROXIMATE-TO-0.1 AND 0-LESS-THAN-OR-EQUAL-TO-Y-LESS-THAN-OR-EQUAL-TO-5) [J].
LI, HS ;
CADOGAN, JM ;
XU, JM ;
DOU, SX ;
LIU, HK .
HYPERFINE INTERACTIONS, 1994, 94 (1-4) :1929-1935