2D GeSe2 amorphous monolayer

被引:6
作者
Zhang, Bo [1 ]
Mikysek, Tomas [3 ]
Cicmancova, Veronika [2 ]
Slang, Stanislav [2 ]
Svoboda, Roman [4 ]
Kutalek, Petr [5 ]
Wagner, Tomas [1 ,2 ]
机构
[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Studentska 573, Pardubice 53210, Czech Republic
[2] Univ Pardubice, Fac Chem Technol, Ctr Mat & Nanotechnol, Nam Cs Legii 565, Pardubice 53002, Czech Republic
[3] Univ Pardubice, Fac Chem Technol, Dept Analyt Chem, Studentska 573, Pardubice 53210, Czech Republic
[4] Univ Pardubice, Fac Chem Technol, Dept Phys Chem, Studentska 573, Pardubice 53210, Czech Republic
[5] Univ Pardubice, Joint Lab Solid State Chem, Studentska 84, Pardubice 53210, Czech Republic
关键词
2D amorphous chalcogenide; SSC-2018; CHALCOGENIDE FILMS; DISSOLUTION; AS2S3; AG;
D O I
10.1515/pac-2019-0501
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper, GeSe2 thin film and glass ingot were prepared in a layered structure. Subsequently, the 2D amorphous monolayers were achieved from layered thin film and layered glass ingot. The thicknesses of monolayers from thin film range from 1.5 nm to 5 nm. And the thickness of monolayer from glass ingot is 7 mu m. The fast cooling of material results in the formation of self-assembled monolayers. In the case of thin film, layers are connected with "bridge". After doping of Ag, the precipitation of nano particles exfoliates the adjacent monolayers which can be further dispersed by etching of Ag particles. In the case of glass ingot, the composition changes at 1% between adjacent monolayers, according to EDX (energy-dispersive X-ray spectroscopy) spectra. And the glass 2D monolayer can be mechanically peeled off from the glass ingot.
引用
收藏
页码:1787 / 1796
页数:10
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