A two-dimensional azido-based topologic ferrimagnet

被引:100
作者
Escuer, A
Mautner, FA
Goher, MAS
Abu-Youssef, MAM
Vicente, R
机构
[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
[2] Graz Tech Univ, Inst Phys & Theoret Chem, A-8010 Graz, Austria
[3] Univ Alexandria, Fac Sci, Dept Chem, Alexandria 21321, Egypt
关键词
D O I
10.1039/b413665a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reported Mn-II - azide system is the first example of a two-dimensional homometallic ferrimagnet, in which the magnetic properties are due exclusively to topological reasons related with the coordinationmode of the bridging ligands; it is also the first case in which a system of this kind exhibits long range order comparable to the classical heterospin ferrimagnets.
引用
收藏
页码:605 / 607
页数:3
相关论文
共 13 条
[1]  
Abu-Youssef MAM, 2000, ANGEW CHEM INT EDIT, V39, P1624, DOI 10.1002/(SICI)1521-3773(20000502)39:9<1624::AID-ANIE1624>3.0.CO
[2]  
2-7
[3]   Topological ferrimagnetic behavior of two new [Mn(L)2(N3)2]n chains with the new AF/AF/F alternating sequence (L=3-methylpyridine or 3,4-dimethylpyridine) [J].
Abu-Youssef, MAM ;
Drillon, M ;
Escuer, A ;
Goher, MAS ;
Mautner, FA ;
Vicente, R .
INORGANIC CHEMISTRY, 2000, 39 (22) :5022-5027
[4]   Synthesis, structural characterization, and Monte Carlo simulation of the magnetic properties of two new alternating MnII azide 2-D honeycombs.: Study of the ferromagnetic ordered phase below 20 K [J].
Escuer, A ;
Cano, J ;
Goher, MAS ;
Journaux, Y ;
Lloret, F ;
Mautner, FA ;
Vicente, R .
INORGANIC CHEMISTRY, 2000, 39 (21) :4688-4695
[5]   Synthesis and structural characterization of the one-dimensional [Cu(3-Clpy)2(N3)2]n complex (3-Clpy = 3-chloropyridine):: A singular ferrimagnetic chain with local SA = SB [J].
Escuer, A ;
Vicente, R ;
El Fallah, MS ;
Goher, MAS ;
Mautner, FA .
INORGANIC CHEMISTRY, 1998, 37 (17) :4466-4469
[6]   Antiferromagnetic alternating and homogeneous manganese-azido chains:: Structural characterization and magnetic behavior of two new one-dimensional [Mn(L)2(μ1,3-N3)2]n compounds (L = 3-ethylpyridine and 2-hydroxypyridine) [J].
Escuer, A ;
Vicente, R ;
Goher, MAS ;
Mautner, FA .
INORGANIC CHEMISTRY, 1998, 37 (04) :782-787
[7]   From achiral ligands to chiral coordination polymers: Spontaneous resolution, weak ferromagnetism, and topological ferrimagnetism [J].
Gao, EQ ;
Yue, YF ;
Bai, SQ ;
He, Z ;
Yan, CH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (05) :1419-1429
[8]  
Goher MAS, 2000, CHEM-EUR J, V6, P778, DOI 10.1002/(SICI)1521-3765(20000303)6:5<778::AID-CHEM778>3.0.CO
[9]  
2-P
[10]   INFLUENCE OF ELECTRON-WITHDRAWING N-1 SUBSTITUENTS ON THE THERMAL-BEHAVIOR OF 5-AZIDO-1,2,3-TRIAZOLES [J].
LABBE, G ;
BEENAERTS, L .
TETRAHEDRON, 1989, 45 (03) :749-756