Neon Adsorption on HKUST-1 and UiO-66 Metal-Organic Frameworks over Wide Pressure and Temperature Ranges

被引：10

作者：

Barreto, Jorge ^{[1
]}

Xavier, Mario D. G. ^{[1
,5
]}

Ribeiro, Rui P. P. L. ^{[2
]}

Martins, Daniel ^{[3
]}

Esteves, Isabel A. A. C. ^{[2
]}

Branco, Moritz ^{[3
,4
]}

Tirolien, Thierry ^{[4
]}

Mota, Jose P. B. ^{[2
]}

Bonfait, Gregoire ^{[1
]}

机构：

[1] Univ Nova Lisboa, Dept Fis, Fac Ciencias & Tecnol, LIBPhys, P-2829516 Caparica, Portugal

[2] Univ Nova Lisboa, Dept Quim, Fac Ciencias & Tecnol, LAQV REQUIMTE, P-2829516 Caparica, Portugal

[3] Act Space Technol SA, Parque Ind Taveiro,Lote 12, P-3045508 Coimbra, Portugal

[4] European Space Agcy, Estec, E0053A, NL-2200 AG Noordwijk, Netherlands

[5] Belgian Nucl Res Ctr, SCK CEN, Boeretang 200, B-2400 Mol, Belgium

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2019年 / 64卷 / 12期

关键词：

CARBON-DIOXIDE; GAS-ADSORPTION; NITROGEN; CO2; HYDROGEN; REMOVAL; DEFECTS; METHANE; STORAGE; CH4;

D O I：

10.1021/acs.jced.9b00606

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Neon (Ne) is an expensive noble gas with commercial interest, which is why systems for Ne storage and delivery are useful tools for its more efficient utilization. Although adsorption-based technologies are potential candidates for the development of such systems, there have been few research efforts on the study of Ne adsorption equilibria on porous solids. Metal-organic frameworks (MOFs) are a recent class of promising porous materials for adsorptive gas storage. In the present work, Ne adsorption in two of the most well-known MOF materials-HKUST-1 and UiO-66-has been evaluated experimentally over unusually wide pressure and temperature ranges: 0-70 bar, 77-400 K for HKUST-1 and 0-100 bar, 77-500 K for UiO-66. HKUST-1 has higher Ne adsorption capacity per unit weight than UiO-66, whereas per unit volume the two materials perform similarly. Moreover, the isosteric heats for Ne adsorption on HKUST-1 and UiO-66 have roughly the same order of magnitude (3-6 kJ/mol).

引用

页码：5407 / 5414

页数：8

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