Systematic Molecular-Level Design of Binders Incorporating Meldrum's Acid for Silicon Anodes in Lithium Rechargeable Batteries

被引:169
作者
Kwon, Tae-woo [1 ,2 ]
Jeong, You Kyeong [1 ,2 ]
Lee, Inhwa [3 ]
Kim, Taek-Soo [3 ]
Choi, Jang Wook [1 ,2 ]
Coskun, Ali [2 ,4 ]
机构
[1] Korea Adv Inst Sci & Technol, Grad Sch EEWS, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, KAIST Inst NanoCentury, Taejon 305701, South Korea
[3] Korea Adv Inst Sci & Technol, Dept Mech Engn, Taejon 305701, South Korea
[4] Korea Adv Inst Sci & Technol, Grad Sch EEWS, Dept Chem, Taejon 305701, South Korea
基金
新加坡国家研究基金会;
关键词
LI-ION BATTERIES; NEGATIVE ELECTRODES; CROSS-LINKING; PERFORMANCE; COMPOSITES; POLYMERS; STORAGE;
D O I
10.1002/adma.201402950
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Covalent or Noncovalent? Systematic investigation of polymeric binders incorporating Meldrum's acid reveals most critical binder properties for silicon anodes in lithium ion batteries, that is self-healing effect facilitated by a series of noncovalent interactions.
引用
收藏
页码:7979 / +
页数:8
相关论文
共 35 条
[1]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[2]   Colossal reversible volume changes in lithium alloys [J].
Beaulieu, LY ;
Eberman, KW ;
Turner, RL ;
Krause, LJ ;
Dahn, JR .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (09) :A137-A140
[3]   Key Parameters Governing the Reversibility of Si/Carbon/CMC Electrodes for Li-Ion Batteries [J].
Bridel, J. -S. ;
Azais, T. ;
Morcrette, M. ;
Tarascon, J. -M. ;
Larcher, D. .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :1229-1241
[4]   In Situ Observation and Long-Term Reactivity of Si/C/CMC Composites Electrodes for Li-Ion Batteries [J].
Bridel, J-S. ;
Azais, T. ;
Morcrette, M. ;
Tarascon, J-M. ;
Larcher, D. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (06) :A750-A759
[5]   Cu-Si Nanocable Arrays as High-Rate Anode Materials for Lithium-Ion Batteries [J].
Cao, Fei-Fei ;
Deng, Jun-Wen ;
Xin, Sen ;
Ji, Heng-Xing ;
Schmidt, Oliver G. ;
Wan, Li-Jun ;
Guo, Yu-Guo .
ADVANCED MATERIALS, 2011, 23 (38) :4415-+
[6]   Virus-Enabled Silicon Anode for Lithium-Ion Batteries [J].
Chen, Xilin ;
Gerasopoulos, Konstantinos ;
Guo, Juchen ;
Brown, Adam ;
Wang, Chunsheng ;
Ghodssi, Reza ;
Culver, James N. .
ACS NANO, 2010, 4 (09) :5366-5372
[7]   Enhanced electrochemical properties of a Si-based anode using an electrochemically active polyamide imide binder [J].
Choi, Nam-Soon ;
Yew, Kyoung Han ;
Choi, Wan-Uk ;
Kim, Sung-Soo .
JOURNAL OF POWER SOURCES, 2008, 177 (02) :590-594
[8]   A low-cost and high performance ball-milled Si-based negative electrode for high-energy Li-ion batteries [J].
Gauthier, Magali ;
Mazouzi, Driss ;
Reyter, David ;
Lestriez, Bernard ;
Moreau, Philippe ;
Guyomard, Dominique ;
Roue, Lionel .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (07) :2145-2155
[9]   Porous Doped Silicon Nanowires for Lithium Ion Battery Anode with Long Cycle Life [J].
Ge, Mingyuan ;
Rong, Jiepeng ;
Fang, Xin ;
Zhou, Chongwu .
NANO LETTERS, 2012, 12 (05) :2318-2323
[10]   Cross-Linked Poly(acrylic acid) with Polycarbodiimide as Advanced Binder for Si/Graphite Composite Negative Electrodes in Li-Ion Batteries [J].
Han, Zhen-Ji ;
Yabuuchi, Naoaki ;
Hashimoto, Shota ;
Sasaki, Takeo ;
Komaba, Shinichi .
ECS ELECTROCHEMISTRY LETTERS, 2013, 2 (02) :A17-A20