Copper and Graphene activated ZnO nanopowders for enhanced photocatalytic and antibacterial activities

被引:83
作者
Ravichandran, K. [1 ]
Chidhambaram, N. [1 ,2 ]
Gobalakrishnan, S. [3 ]
机构
[1] AVVM Sri Pushpam Coll Autonomous, Post Grad & Res Dept Phys, Thanjavur 613503, Tamil Nadu, India
[2] Rajah Serfoji Govt Coll Autonomous, Post Grad & Res Dept Phys, Thanjavur 613503, Tamil Nadu, India
[3] Noorul Islam Univ, Dept Nanotechnol, Noorul Islam Ctr Higher Educ, Kumaracoil 629180, Tamil Nadu, India
关键词
Oxides; Wet Chemical; X-ray diffraction; luminescence; defects; AG/ZNO NANOCOMPOSITES; THIN-FILMS; DEGRADATION; COMPOSITE; OXIDE; NANOPARTICLES; CU; EFFICIENCY; PLATFORM;
D O I
10.1016/j.jpcs.2016.02.013
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
ZnO, ZnO:Cu and ZnO:Cu:Graphene nanopowders were synthesized via a facile wet chemical method. The XRD studies show that the synthesized samples have hexagonal wurtzite structure. It is found that graphene addition induces a decrease in crystallite size. UV-vis absorption spectra of the samples show sharp absorption edges around 380 nm. Photoluminescence studies reveal that the incorporation of copper and graphene in ZnO facilitates the efficient photo generated electron-hole pair separation. It is found that the ZnO:Cu and ZnO:Cu:Graphene nanopowder exhibit improved photocatalytic efficiency for the photodegradation of Methylene Blue (MB) under visible light irradiation. Moreover, improved antibacterial activity of ZnO:Cu:Graphene nanopowder against Escherichia coli and Staphylococcus aureus bacteria is observed. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:82 / 90
页数:9
相关论文
共 43 条
[21]   A promising electrochemical sensing platform based on ternary composite of polyaniline-Fe2O3-reduced graphene oxide for sensitive hydroquinone determination [J].
Radhakrishnan, Sivaprakasam ;
Krishnamoorthy, Karthikeyan ;
Sekar, Chinnathambi ;
Wilson, Jeyaraj ;
Kim, Sang Jae .
CHEMICAL ENGINEERING JOURNAL, 2015, 259 :594-602
[22]   Size-Dependent Bacterial Growth Inhibition and Mechanism of Antibacterial Activity of Zinc Oxide Nanoparticles [J].
Raghupathi, Krishna R. ;
Koodali, Ranjit T. ;
Manna, Adhar C. .
LANGMUIR, 2011, 27 (07) :4020-4028
[23]   Enhancing the photocatalytic efficiency of sprayed ZnO thin films through double doping (Sn plus F) and annealing under different ambiences [J].
Ravichandran, K. ;
Mohan, R. ;
Sakthivel, B. ;
Varadharajaperumal, S. ;
Devendran, P. ;
Alagesan, T. ;
Pandian, K. .
APPLIED SURFACE SCIENCE, 2014, 321 :310-317
[24]   Enhancement in the antibacterial efficiency of ZnO nanopowders by tuning the shape of the nanograins through fluorine doping [J].
Ravichandran, K. ;
Snega, S. ;
Begum, N. Jabena ;
Swaminathan, K. ;
Sakthivel, B. ;
Christena, L. Rene ;
Chandramohan, G. ;
Ochiai, Shizuyasu .
SUPERLATTICES AND MICROSTRUCTURES, 2014, 69 :17-28
[25]   Synthesis of Ag/ZnO nanorods array with enhanced photocatalytic performance [J].
Ren, Chunlei ;
Yang, Beifang ;
Wu, Min ;
Xu, Jiao ;
Fu, Zhengping ;
Lv, Yan ;
Guo, Ting ;
Zhao, Yongxun ;
Zhu, Changqiong .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 182 (1-3) :123-129
[26]   Synthesis and investigation of Indium doping and surfactant on the morphological, optical and UV/Vis photocatalytic properties of ZnO nanostructure [J].
Rezapour, Mehdi ;
Talebian, Nasrin .
CERAMICS INTERNATIONAL, 2014, 40 (02) :3453-3460
[27]   Enhanced photocatalytic activity of ZnO/CuO nanocomposite for the degradation of textile dye on visible light illumination [J].
Saravanan, R. ;
Karthikeyan, S. ;
Gupta, V. K. ;
Sekaran, G. ;
Narayanan, V. ;
Stephen, A. .
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2013, 33 (01) :91-98
[28]   The reduction of graphene oxide by zinc powder to produce a zinc oxide-reduced graphene oxide hybrid and its superior photocatalytic activity [J].
Sarkar, Sanjit ;
Basak, Durga .
CHEMICAL PHYSICS LETTERS, 2013, 561 :125-130
[29]   Cu-doped ZnO nanoparticles: Synthesis, structural and electrical properties [J].
Singhal, Sonal ;
Kaur, Japinder ;
Namgyal, Tsering ;
Sharma, Rimi .
PHYSICA B-CONDENSED MATTER, 2012, 407 (08) :1223-1226
[30]   Synthesis of ZnFe2O4/ZnO nanocomposites immobilized on graphene with enhanced photocatalytic activity under solar light irradiation [J].
Sun, Lin ;
Shao, Rong ;
Tang, Lanqin ;
Chen, Zhidong .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 564 :55-62