Multi-walled carbon nanotube dispersion methodologies in alkaline media and their influence on mechanical reinforcement of alkali-activated nanocomposites

被引：30

作者：

Davoodabadi, Maliheh ^{[1
,2
,3
]}

Liebscher, Marco ^{[2
]}

Hampel, Silke ^{[3
]}

Sgarzi, Massimo ^{[4
,5
]}

Rezaie, Ali Bashiri ^{[2
]}

Wolf, Daniel ^{[3
]}

Cuniberti, Gianaurelio ^{[4
,5
,6
,7
]}

Mechtcherine, Viktor ^{[2
]}

Yang, Jian ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Naval Architecture Ocean & Civil Engn, Dept Civil Engn, Shanghai 200240, Peoples R China

[2] Tech Univ Dresden, Inst Construct Mat, Fac Civil Engn, D-01069 Dresden, Germany

[3] Leibniz Inst Solid State & Mat Res, D-01069 Dresden, Germany

[4] Tech Univ Dresden, Inst Mat Sci, D-01069 Dresden, Germany

[5] Tech Univ Dresden, Max Bergmann Ctr Biomat, D-01069 Dresden, Germany

[6] Tech Univ Dresden, Ctr Adv Elect Dresden CfAED, D-01069 Dresden, Germany

[7] Tech Univ Dresden, Dresden Ctr Computat Mat Sci DCMS, D-01069 Dresden, Germany

来源：

COMPOSITES PART B-ENGINEERING | 2021年 / 209卷

关键词：

Carbon nanotubes; Alkali-activated materials; Nanofluids; Nanocomposites; Colloidal interactions; Mechanical properties; Microstructure; AQUEOUS-SOLUTION; CEMENTITIOUS COMPOSITES; VIBRATIONAL-SPECTRA; FLY-ASH; ADSORPTION; GRAPHENE; NAPHTHALENE; SLAG; SHRINKAGE; SILICA;

D O I：

10.1016/j.compositesb.2020.108559

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The focus of present research is the establishment of a practical procedure for effective incorporation of multi-walled carbon nanotubes (MWCNTs) into alkali-activated materials (AAMs) with the aim of mechanical reinforcement. Investigated composite in this work was an alkali-activated matrix composed of fly ash (FA) and ground-granulated blast furnace-slag (GGBS) as solid aluminium-calcium-silicate precursors along with highly concentrated sodium silicate (Na2SiO3) and sodium hydroxide (NaOH) as liquid alkaline activators. Na2SiO3, NaOH, and a combination of them were used for dispersion of MWCNTs. An anionic surfactant, naphthalene sulfonate (NS), and ultrasonication were applied to assist in the preparation of nanofluids. Optical microscopy, integral light transmission (ILT), and Fourier-transform infrared spectroscopy (FTIR) were performed to assess the colloidal behaviour of MWCNTs in the nanofluids. The possible dispersion mechanisms were furthermore hypothesised for each alkaline medium. Based on the outcomes, MWCNTs had the best dispersion performance in the Na2SiO3 based nanofluids. The relevant nanocomposites accordingly, in comparison to the other preparation methodologies in this research, indicated the highest improvements in flexural (65%) and compressive (30%) strengths as a consequence of 0.050 wt% MWCNT incorporation. Scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) further clarified the reinforcement functionality and microstructure refinement of the MWCNTs dispersed in the Na2SiO3 based nanofluids. Altogether, this paper represents a broad insight concerning a better understanding of MWCNTs' interactions in alkaline activators, i.e. dispersion media, and AAMs, i.e. host matrices, to obtain the highest possible mechanical and microstructural performance of reinforced nanocomposites.

引用

页数：16

共 88 条

[61] Effect of superplasticizer and shrinkage-reducing admixtures on alkali-activated slag pastes and mortars [J].