Cross-metathesis of propane and methane:: A catalytic reaction of C-C bond cleavage of a higher alkane by methane

被引：56

作者：

Soulivong, D

Copéret, C

Thivolle-Cazat, J

Basset, JM

Maunders, BM

Pardy, RBA

Sunley, GJ

机构：

[1] Ecole Super Chim Phys & Elect, UMR 9986, Lab Surface Organomet Chem, F-69616 Villeurbanne, France

[2] BP Chem Ltd, Sunbury On Thames TW16 7LN, Middx, England

[3] BP Chem Ltd, Hull Res & Technol Ctr, Kingston Upon Hull HU12 8DS, N Humberside, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 40期

关键词：

alkanes; cross-metathesis; heterogeneous catalysis; methane homologation; tantalum;

D O I：

10.1002/anie.200460982

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methane, a building block for basic chemicals through its incorporation into alkanes: when a methane/propane mixture is passed over a tantalum hydride catalyst at 250°C, propane is transformed into two ethane molecules through the incorporation of one methane unit. This reaction corresponds to a cross-metathesis of propane and methane (see scheme; Alk = alkyl).

引用

页码：5366 / 5369

页数：4

共 27 条

[1]

[Anonymous], 2001, ANGEW CHEM, V113, P2393

[2] SELECTIVE INTERMOLECULAR CARBON-HYDROGEN BOND ACTIVATION BY SYNTHETIC METAL-COMPLEXES IN HOMOGENEOUS SOLUTION [J].

ARNDTSEN, BA ;

BERGMAN, RG ;

MOBLEY, TA ;

PETERSON, TH .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) :154-162

[3]

Chabanas M, 2000, ANGEW CHEM INT EDIT, V39, P1962, DOI 10.1002/1521-3773(20000602)39:11<1962::AID-ANIE1962>3.0.CO

[4]

2-1

[5]

Chabanas M., 2000, ANGEW CHEM, V112, P2038

[6] Low-temperature nonoxidative activation of methane over H-galloaluminosilicate (MFI) zeolite [J].

Choudhary, VR ;

Kinage, AK ;

Choudhary, TV .

SCIENCE, 1997, 275 (5304) :1286-1288

[7] Homogeneous and heterogeneous catalysis:: Bridging the gap through surface organometallic chemistry [J].

Copéret, C ;

Chabanas, M ;

Saint-Arroman, RP ;

Basset, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (02) :156-181

[8]

Copéret C, 2001, ANGEW CHEM INT EDIT, V40, P2331, DOI 10.1002/1521-3773(20010618)40:12<2331::AID-ANIE2331>3.0.CO

[9]

2-P

[10]

Coperet C., 2003, ANGEW CHEM, V115, P164, DOI [DOI 10.1002/ANGE.200390040, 10.1002/ange.200390040]

← 1 2 3 →