Catalytic hydrogenation of Low temperature coal tar into jet fuel by using two-reactors system

被引:24
作者
Gang, Yong [1 ,2 ]
Pan, Liuyi [1 ,2 ]
Niu, Menglong [3 ]
Zhang, Xu [1 ]
Li, Dong [1 ,2 ]
Li, Wenhong [1 ,2 ]
机构
[1] Northwest Univ, Sch Chem Engn, Xian 710069, Shaanxi, Peoples R China
[2] Shaanxi Res Ctr Chem Engn Technol Resource Utiliz, Xian 710069, Shaanxi, Peoples R China
[3] Xian Shiyou Univ, Sch Chem & Chem Engn, Xian 710065, Shaanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Coal tar; Catalyst; Hydrogenation; Jet fuel; SELECTIVE HYDROISOMERIZATION; N-ALKANES; DISTILLATE; PT/SAPO-11; CONVERSION; KINETICS;
D O I
10.1016/j.jaap.2018.06.009
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The experiment of the jet fuel fraction through hydrogenation was investigated via hydrogenation in two-stage fixed beds reactor filled with hydrofining catalyst and hydroisomerization catalyst with low-temperature coal tar (LTCT) distillate (< 360 degrees C) as the feedstock. The reaction of coal tar on the catalyst was studied through analyzing the yield of product, the saturation performance, the carbon number distribution and the chemical components of the jet fuel fraction. In current study, the experimental conditions included the temperature at 340 similar to 400 degrees C, the pressure of 6 similar to 12 MPa and the liquid hourly space velocity (LHSV) of 0.4 similar to 1.0 h (-1). The results showed that at a fixed pressure (10 MPa), reaction temperature (380 degrees C), LHSV (0.8 h(-1)) and the H-2/oil ratio of (1600:1), the yield of the jet fuel fraction and the content of saturated hydrocarbons in the prodcuts were 58.0% and 60.7%, respectively. Finally, by GC-MS analysis, cyclanes and i-alkanes were dominant components in the jet fuel fraction, approximately accounting for 63.08% and 20.25%, respectively.
引用
收藏
页码:202 / 208
页数:7
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