Catalytic Membrane Reactors: The Industrial Applications Perspective

被引:38
作者
Algieri, Catia [1 ]
Coppola, Gerardo [2 ]
Mukherjee, Debolina [2 ]
Shammas, Mahaad Issa [3 ]
Calabro, Vincenza [2 ]
Curcio, Stefano [2 ]
Chakraborty, Sudip [2 ]
机构
[1] Natl Res Council Italy ITM CNR, Inst Membrane Technol, Cubo 17C,Via Pietro Bucci, I-87036 Arcavacata Di Rende, Italy
[2] Univ Calabria, Dept DIMES, Via Pietro Bucci,Cubo 42A, I-87036 Arcavacata Di Rende, Italy
[3] Dhofar Univ, Dept Civil & Environm Engn, Salalah, Sultanate, Oman
关键词
catalysis; membrane reactor; process intensification; inorganic catalyst; enzyme; environmental applications; WASTE-WATER TREATMENT; GAS-SHIFT REACTION; MICROBIAL FUEL-CELL; FISCHER-TROPSCH SYNTHESIS; HOLLOW-FIBER MEMBRANES; PALLADIUM-BASED MEMBRANES; MFI ZEOLITE MEMBRANES; PD-BASED MEMBRANE; OXIDATIVE DEHYDROGENATION; SELECTIVE OXIDATION;
D O I
10.3390/catal11060691
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Catalytic membrane reactors have been widely used in different production industries around the world. Applying a catalytic membrane reactor (CMR) reduces waste generation from a cleaner process perspective and reduces energy consumption in line with the process intensification strategy. A CMR combines a chemical or biochemical reaction with a membrane separation process in a single unit by improving the performance of the process in terms of conversion and selectivity. The core of the CMR is the membrane which can be polymeric or inorganic depending on the operating conditions of the catalytic process. Besides, the membrane can be inert or catalytically active. The number of studies devoted to applying CMR with higher membrane area per unit volume in multi-phase reactions remains very limited for both catalytic polymeric and inorganic membranes. The various bio-based catalytic membrane system is also used in a different commercial application. The opportunities and advantages offered by applying catalytic membrane reactors to multi-phase systems need to be further explored. In this review, the preparation and the application of inorganic membrane reactors in the different catalytic processes as water gas shift (WGS), Fisher Tropsch synthesis (FTS), selective CO oxidation (CO SeLox), and so on, have been discussed.
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页数:22
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