Practical olefin metathesis in protic media under an air atmosphere

被引:68
作者
Connon, SJ [1 ]
Rivard, M [1 ]
Zaja, M [1 ]
Blechert, S [1 ]
机构
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
关键词
catalysis; metathesis; olefins; ruthenium; water;
D O I
10.1002/adsc.200202201
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The discovery that efficient olefin metathesis reactions involving previously challenging terminal olefin substrates are possible using novel and readily available catalyst systems in non-distilled, non-degassed protic media in air is reported.
引用
收藏
页码:572 / 575
页数:4
相关论文
共 36 条
  • [11] Olefin metathesis-active ruthenium complexes bearing a nucleophilic carbene ligand
    Huang, JK
    Stevens, ED
    Nolan, SP
    Petersen, JL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (12) : 2674 - 2678
  • [12] Ruthenium catalysed cross metathesis with fluorinated olefins
    Imhof, S
    Randl, S
    Blechert, S
    [J]. CHEMICAL COMMUNICATIONS, 2001, (17) : 1692 - 1693
  • [13] Ring-closing metathesis in methanol and water
    Kirkland, TA
    Lynn, DM
    Grubbs, RH
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (26) : 9904 - 9909
  • [14] Novel reactivity of ruthenium alkylidenes in protic solvents: Degenerate alkylidene proton exchange
    Lynn, DM
    Grubbs, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (14) : 3187 - 3193
  • [15] Water-soluble ruthenium alkylidenes: Synthesis, characterization, and application to olefin metathesis in protic solvents
    Lynn, DM
    Mohr, B
    Grubbs, RH
    Henling, LM
    Day, MW
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (28) : 6601 - 6609
  • [16] Living ring-opening metathesis polymerization in water
    Lynn, DM
    Mohr, B
    Grubbs, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (07) : 1627 - 1628
  • [17] Living ring-opening metathesis polymerization in aqueous media catalyzed by well-defined ruthenium carbene complexes
    Lynn, DM
    Kanaoka, S
    Grubbs, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (04) : 784 - 790
  • [18] Synthesis of water-soluble, aliphatic phosphines and their application to well-defined ruthenium olefin metathesis catalysts
    Mohr, B
    Lynn, DM
    Grubbs, RH
    [J]. ORGANOMETALLICS, 1996, 15 (20) : 4317 - 4325
  • [19] Selective olefin metatheses - new tools for the organic chemist: A review
    Randall, ML
    Snapper, ML
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1998, 133 (1-2) : 29 - 40
  • [20] Randl S, 2001, SYNLETT, P430