Practical olefin metathesis in protic media under an air atmosphere

被引：68

作者：

Connon, SJ ^{[1
]}

Rivard, M ^{[1
]}

Zaja, M ^{[1
]}

Blechert, S ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2003年 / 345卷 / 05期

关键词：

catalysis; metathesis; olefins; ruthenium; water;

D O I：

10.1002/adsc.200202201

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The discovery that efficient olefin metathesis reactions involving previously challenging terminal olefin substrates are possible using novel and readily available catalyst systems in non-distilled, non-degassed protic media in air is reported.

引用

页码：572 / 575

页数：4

共 36 条

[1] Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM
Ackermann, L
Fürstner, A
Weskamp, T
Kohl, FJ
Herrmann, WA
[J]. TETRAHEDRON LETTERS, 1999, 40 (26) : 4787 - 4790
[2] Chemoselective cross-metathesis reaction. Application to the synthesis of the C1-C14 fragment of amphidinol 3
BouzBouz, S
Cossy, J
[J]. ORGANIC LETTERS, 2001, 3 (10) : 1451 - 1454
[3] A solid-supported phosphine-free ruthenium alkylidene for olefin metathesis in methanol and water
Connon, SJ
Blechert, S
[J]. BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2002, 12 (14) : 1873 - 1876
[4] Cross-metathesis reaction. Generation of highly functionalized olefins from unsaturated alcohols (vol 624, pg 327, 2001)
Cossy, J
BouzBouz, S
Hoveyda, AH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 634 (02) : 215 - 221
[5] Olefin metathesis in non-degassed solvent using a recyclable, polymer supported alkylideneruthenium
Dowden, J
Savovic, J
[J]. CHEMICAL COMMUNICATIONS, 2001, (01) : 37 - 38
[6] Fürstner A, 2000, ANGEW CHEM INT EDIT, V39, P3012
[7] Furstner A., 2000, ANGEW CHEM, V112, P3140
[8] Efficient and recyclable monomeric and dendritic Ru-based metathesis catalysts
Garber, SB
Kingsbury, JS
Gray, BL
Hoveyda, AH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (34) : 8168 - 8179
[9] Synthesis and metathesis reactions of a phosphine-free dihydroimidazole carbene ruthenium complex
Gessler, S
Randl, S
Blechert, S
[J]. TETRAHEDRON LETTERS, 2000, 41 (51) : 9973 - 9976
[10] Recent advances in olefin metathesis and its application in organic synthesis
Grubbs, RH
Chang, S
[J]. TETRAHEDRON, 1998, 54 (18) : 4413 - 4450

← 1 2 3 4 →