Assessment of micro-structured fixed-bed reactors for highly exothermic gas-phase reactions

The application of micro-structured fixed-bed reactors for highly exothermic partial oxidation reactions and their comparison to established multi-tubular fixed-bed reactors was investigated by numerical simulation. As examples, the partial oxidations of butane to maleic anhydride and of o-xylene to phthalic anhydride were chosen. The simulation results revealed that the reactor productivity, i.e. the amount of product per unit of reactor volume, achievable in micro-structured fixed-bed reactors is between 2.5 and 7 times higher than in conventional multi-tubular fixed-bed reactors without the danger of excessive pressure drop. For the partial oxidation of butane to maleic anhydride this can be explained by the increased reactor efficiency caused by lower efficiency losses through heat and mass transfer limitations. In addition, maleic anhydride selectivities and yields are higher in micro-structured fixed-bed reactors. In the case of o-xylene oxidation to phthalic anhydride the main advantage is that egg-shell catalysts in the conventional fixed-bed reactor can be replaced by bulk catalysts in the microstructured fixed-bed reactor. For this reaction, product selectivities are very similar for all reactor configurations. Thus the catalyst inventory and reactor productivity are strongly increased. This study underlines, that micro-structured fixed-bed reactors exhibit the potential to intensify large scale industrial processes significantly. (C) 2009 Elsevier Ltd. All rights reserved.