Ruthenium-birhodanine complex supported over fibrousphosphosilicate for photocatalytic CO2 reduction to formate

被引：12
作者：
Zhiani, Rahele [1 ]
Khoobi, Mehdi [2 ,3 ]
Sadeghzadeh, Seyed Mohsen [1 ]
机构：
[1] Islamic Azad Univ, Fac Sci, Dept Chem, Neyshabur Branch, Neyshabur, Iran
[2] Univ Tehran Med Sci, Inst Pharmaceut Sci, Tehran 1417614411, Iran
[3] Univ Tehran Med Sci, Fac Pharm, Dept Pharmaceut Biomat, Tehran, Iran
来源：
CATALYSIS TODAY | 2020年 / 340卷
关键词：
Phosphosilicate; KCC-1; Nano catalyst; One-pot synthesis; Green chemistry; Nanoparticle; AZIDE-ALKYNE CYCLOADDITION; METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE REDUCTION; CLICK CHEMISTRY; EFFICIENT; CATALYSTS; 1,2,3-TRIAZOLES; CONSTRUCTION; EVOLUTION; POLYMERS;
D O I：
10.1016/j.cattod.2018.09.034
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
In this work we report the design and synthesis of high-surface-area nanocatalysts by reaction between tripolyphosphate (TPP) and tetraethyl orthosilicate (TEOS) and then the complex ruthenium acetate anchored over the click modified ligand of fibrous phosphosilicate (FPS), forms a new highly efficient nano catalyst that shows excellent catalytic performance within CO2 reduction to formate under visible-light irradiation. The FPS/Ligand/Ru nanocatalyst was thoroughly characterized by Fourier transform infrared spectra (FTIR), Powder X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Transmission electron microscopy (TEM), Energy dispersive X-ray spectroscopy (EDX), and N-2 adsorption/desorption study.
引用
收藏
页码：197 / 203
页数：7
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