Carbon Nanofiber-Based Palladium/Zinc Catalysts for the Hydrogenation of Carbon Dioxide to Methanol at Atmospheric Pressure

被引：40

作者：

Diez-Ramirez, Javier ^{[1
]}

Sanchez, Paula ^{[1
]}

Rodriguez-Gomez, Alberto ^{[1
]}

Luis Valverde, Jose ^{[1
]}

Dorado, Fernando ^{[1
]}

机构：

[1] Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim, Dept Ingn Quim, Avenida Camilo Jose Cela 12, E-13071 Ciudad Real, Spain

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2016年 / 55卷 / 12期

关键词：

FISCHER-TROPSCH SYNTHESIS; CO2; HYDROGENATION; COBALT CATALYSTS; PD/ZNO; PD; ZNO; NANOTUBES; ALLOYS; CONVERSION; REDUCTION;

D O I：

10.1021/acs.iecr.6b00170

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Palladium/zinc catalysts supported on carbon nanofibers (CNFs) have been used to study the catalytic performance in the hydrogenation of CO2 to obtain methanol at atmospheric pressure. The carbon nanofiber support has an influence, on the nature of the PdZn alloy formed. The effect of the Pd/Zn molar ratio on the PdZn alloy particle size was analyzed. Lower Pd/Zn molar ratio leads to higher PdZn alloy particle size, which was associated with higher selectivity toward methanol. The influence of the type of nanofiber (platelet or fishbone) on the catalytic behavior was also studied and compared with that of a conventional Pd/ZnO catalyst. The palladium/zinc catalyst supported on platelet nanofiber was considered to be a good candidate for the hydrogenation of carbon dioxide to methanol.

引用

页码：3556 / 3567

页数：12

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