共 7 条
MoP nanosheets supported on biomass-derived carbon flake: One-step facile preparation and application as a novel high-active electrocatalyst toward hydrogen evolution reaction
被引:234
|作者:
Cui, Wei
[1
,2
]
Liu, Qian
[1
]
Xing, Zhicai
[1
]
Asiri, Abdullah M.
[3
,4
]
Alamry, Khalid A.
[3
,4
]
Sun, Xuping
[1
,3
,4
]
机构:
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia
[4] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, Jeddah 21589, Saudi Arabia
基金:
中国国家自然科学基金;
关键词:
MoP nanosheets;
Carbon flake;
Biomass;
Hydrogen evolution reaction electrocatalyst;
Acidic and neutral electrolytes;
NICKEL PHOSPHIDE;
COUNTER ELECTRODE;
CATALYST;
GRAPHENE;
MOS2;
FE;
HYDRODEOXYGENATION;
4-METHYLPHENOL;
NITRIDE;
SITE;
D O I:
10.1016/j.apcatb.2014.09.016
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Searching for Pt-free hydrogen evolution reaction (HER) electrocatalysts based on low-cost and eartha-bundant materials is a crucial task for hydrogen-based energy industry. In this work, we demonstrate the one-step facile preparation of MoP nanosheets supported on carbon flake via a solid-state reaction with the use of (NH4)(6)Mo7O24 center dot 4H(2)O, NaH2PO4 center dot 2H(2)O and a biomass, sodium alginate, as Mo, P and C sources, respectively. When used as a novel HER electrocatalyst, such composites are excellent in activity and durability in acidic electrolytes. Moreover, they are also active in neutral electrolytes. (C) 2014 Elsevier B.V. All rights reserved.
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页码:144 / 150
页数:7
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