Green Polymer Electrolytes based on Chitosan and 1-butyl-3-methylimidazolium acetate

被引：7

作者：

Shamsudin, Intan Juliana ^{[1
]}

Ahmad, Azizan ^{[2
]}

Hassan, Nur Hasyareeda ^{[2
]}

机构：

[1] Natl Def Univ Malaysia, Dept Chem, Ctr Def Fdn Studies, Kuala Lumpur 57000, Malaysia

[2] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Chem Sci & Food Technol, Bangi 43600, Malaysia

来源：

2014 UKM FST POSTGRADUATE COLLOQUIUM: PROCEEDINGS OF THE UNIVERSITI KEBANGSAAN MALAYSIA, FACULTY OF SCIENCE AND TECHNOLOGY 2014 POSTGRADUATE COLLOQUIUM | 2014年 / 1614卷

关键词：

Chitosan; ionic liquid; polymer electrolytes; ionic conductivity; IONIC LIQUIDS; PLASTICIZERS;

D O I：

10.1063/1.4895229

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Green polymer electrolytes based on chitosan as the polymer matrix and ionic liquid 1-butyl-3-methylimidazolium acetate [Bmim][OAc] as charge carriers were prepared by solution casting technique. Complexes with various amount of ionic liquid loading were investigated as possible ionic conducting polymers. The ionic conductivity was found to increase with increasing weight percent of ionic liquid. The highest ionic conductivity of the charged chitosan-[Bmim][OAc] was 2.44 x 10(-3) S cm(-1) at 90 wt.% of [Bmim][OAc] content at ambient temperature. Attenuated Total Reflection Fourier Transform infrared (ATR-FTIR) spectroscopy has proven the interaction between chitosan and [Bmim][OAc]. X-ray Diffraction (XRD) has shown that the amorphosity of the complexes increase as the amount of [Bmim][OAc] increase.

引用

页码：393 / 398

页数：6

共 50 条

[1] Physicochemical properties of 1-butyl-3-methylimidazolium acetate
Bogolitsyn, K. G.
Skrebets, T. E.
Makhova, T. A.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2009, 79 (01) : 125 - 128
[2] Preparation and characterization of poly (ethyl methacrylate) based polymer electrolytes doped with 1-butyl-3-methylimidazolium trifluoromethanesulfonate
Ramesh, S.
Uma, O.
Shanti, R.
Yi, Lim Jing
Ramesh, K.
MEASUREMENT, 2014, 48 : 263 - 273
[3] Physicochemical properties of 1-butyl-3-methylimidazolium acetate
K. G. Bogolitsyn
T. E. Skrebets
T. A. Makhova
Russian Journal of General Chemistry, 2009, 79 : 125 - 128
[4] Polymer Electrolyte based on Crosslinked Poly(glycidyl methacrylate) and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide
Fei, Beatrice Wong Chui
Abu Hanifah, Sharina
Ahmad, Azizan
Hassan, Nur Hasyareeda
2015 UKM FST POSTGRADUATE COLLOQUIUM, 2015, 1678
[5] The synergistic effect of 1-butyl-3-methylimidazolium chloride and glycerol on the performance of chitosan films
Li, Ning
Liu, Chang
Niu, Li
Li, Xu
Feng, Jacko
Liu, Zhiming
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2025, 302
[6] Effect of ionic liquid 1-butyl-3-methylimidazolium bromide on ionic conductivity of poly(ethyl methacrylate) based polymer electrolytes
Francis, Katherine A.
Liew, Chiam-Wen
Ramesh, S.
Ramesh, K.
Ramesh, S.
MATERIALS EXPRESS, 2016, 6 (03) : 252 - 258
[7] Enhancement on H plus carriers in conduction properties with addition of 1-butyl-3-Methylimidazolium chloride based alginate polymer electrolytes
Fuzlin, A. F.
Mazuki, N. F.
Hasan, Md. Mahmudul
Nagao, Y.
Samsudin, A. S.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 60 : 201 - 211
[8] Carboxymethyl chitin doped 1-butyl-3-methylimidazolium chloride based solid polymer electrolyte
Latifi, M.
Ahmad, A.
Hassan, N. H.
Ben Youcef, H.
Kaddami, H.
MATERIALS TODAY-PROCEEDINGS, 2021, 36 : 16 - 21
[9] Impact of 1-butyl-3-methylimidazolium chloride on the electrospinning of cellulose acetate nanofibers
Javed, Kashif
Krumme, Andres
Krasnou, Illia
Mikli, Valdek
Viirsalu, Mihkel
Plamus, Tiia
Vassiljeva, Viktoria
Tarasova, Elvira
Savest, Natalja
Mendez, James D.
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2018, 55 (02): : 142 - 147
[10] Application of the interstice model to structure characterization of 1-butyl-3-methylimidazolium acetate
K. G. Bogolitsyn
T. A. Makhova
T. E. Skrebets
Russian Journal of General Chemistry, 2010, 80 : 1355 - 1357

← 1 2 3 4 5 →