Oriented Two-Dimensional Covalent Organic Framework Films for Near-Infrared Electrochromic Application

被引：207
作者：
Hao, Qing [1 ,3 ]
Li, Zhi-Juan [2 ,3 ]
Lu, Cheng [1 ,3 ]
Sun, Bing [1 ,4 ]
Zhong, Yu-Wu [2 ,3 ]
Wan, Li-Jun [1 ,3 ]
Wang, Dong [1 ,3 ]
机构：
[1] Chinese Acad Sci, Key Lab Mol Nanostruct & Nanotechnol, CAS Res Educ Ctr Excellence Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Res Educ Ctr Excellence Mol Sci, Key Lab Photochem,Inst Chem, Beijing 100190, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[4] China Univ Geosci Beijing, Sch Sci, Beijing 100083, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 141卷 / 50期
基金：
国家重点研发计划; 中国国家自然科学基金;
关键词：
POLYMERS; TRIPHENYLAMINE; ACCEPTOR; GREEN; RED; EFFICIENT; ARAMIDS; CARBON; SITES; BLUE;
D O I：
10.1021/jacs.9b09956
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The electrochromic property and device construction of a triphenylamine-based oriented two-dimensional covalent organic framework (2D COF) film on indium tin oxide (ITO) coated glass was reported. The characterization of the 2D COF3PA-TT film revealed that the film was uniform, with good crystallinity, and oriented with its 2D plane parallel to the substrate. For the first time, the electrochromic properties of 2D COF3PA-TT film were studied. 2D COF3PA-TT film on ITO exhibited reversible color transition between deep red and dark brown during redox process. Spectroelectrochemical experiments revealed color changes in the absorption spectra of 2D COF3PA-TT film in the visible and near-infrared regions and showed the characteristics of intervalence charge transfer. The quasi-solid-state electrochromic device was prepared based on the COF3PA-TT film, and it exhibited moderate performance and stability in the near-infrared region.
引用
收藏
页码：19831 / 19838
页数：8
相关论文
共 68 条
[1]   Propylenedioxythiophene (ProDOT)-phenylene copolymers allow a yellow-to-transmissive electrochrome [J].
Amb, Chad M. ;
Kerszulis, Justin A. ;
Thompson, Emily J. ;
Dyer, Aubrey L. ;
Reynolds, John R. .
POLYMER CHEMISTRY, 2011, 2 (04) :812-814
[2]   Dioxypyrrole-Based Polymers via Dehalogenation Polycondensation Using Various Electrophilic Halogen Sources [J].
Arroyave, Frank A. ;
Reynolds, John R. .
MACROMOLECULES, 2012, 45 (15) :5842-5849
[3]   Perylene-Based Covalent Organic Frameworks for Acid Vapor Sensing [J].
Ascherl, Laura ;
Evans, Emrys W. ;
Gorman, Jeffrey ;
Orsborne, Sarah ;
Bessinger, Derya ;
Bein, Thomas ;
Friend, Richard H. ;
Auras, Florian .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (39) :15693-15699
[4]   Solvatochromic covalent organic frameworks [J].
Ascherl, Laura ;
Evans, Emrys W. ;
Hennemann, Matthias ;
Di Nuzzo, Daniele ;
Hufnagel, Alexander G. ;
Beetz, Michael ;
Friend, Richard H. ;
Clark, Timothy ;
Bein, Thomas ;
Auras, Florian .
NATURE COMMUNICATIONS, 2018, 9
[5]   Molecular docking sites designed for the generation of highly crystalline covalent organic frameworks [J].
Ascherl, Laura ;
Sick, Torben ;
Margraf, Johannes T. ;
Lapidus, Saul H. ;
Calik, Mona ;
Hettstedt, Christina ;
Karaghiosoff, Konstantin ;
Doeblinger, Markus ;
Clark, Timothy ;
Chapman, Karena W. ;
Auras, Florian ;
Bein, Thomas .
NATURE CHEMISTRY, 2016, 8 (04) :310-316
[6]   Color Control in π-Conjugated Organic Polymers for Use in Electrochromic Devices [J].
Beaujuge, Pierre M. ;
Reynolds, John R. .
CHEMICAL REVIEWS, 2010, 110 (01) :268-320
[7]   Covalent organic frameworks derived hollow structured N-doped noble carbon for asymmetric-electrolyte Zn-air battery [J].
Cai, Pingwei ;
Peng, Xinxin ;
Huang, Junheng ;
Jia, Jingchun ;
Hu, Xiang ;
Wen, Zhenhai .
SCIENCE CHINA-CHEMISTRY, 2019, 62 (03) :385-392
[8]   Tunable electrical conductivity in oriented thin films of tetrathiafulvalene-based covalent organic framework [J].
Cai, Song-Liang ;
Zhang, Yue-Biao ;
Pun, Andrew B. ;
He, Bo ;
Yang, Jinhui ;
Toma, Francesca M. ;
Sharp, Ian D. ;
Yaghi, Omar M. ;
Fan, Jun ;
Zheng, Sheng-Run ;
Zhang, Wei-Guang ;
Liu, Yi .
CHEMICAL SCIENCE, 2014, 5 (12) :4693-4700
[9]   Extraction of Photogenerated Electrons and Holes from a Covalent Organic Framework Integrated Heterojunction [J].
Calik, Mona ;
Auras, Florian ;
Salonen, Laura M. ;
Bader, Kathrin ;
Grill, Irene ;
Handloser, Matthias ;
Medina, Dana D. ;
Dogru, Mirjam ;
Loebermann, Florian ;
Trauner, Dirk ;
Hartschuh, Achim ;
Bein, Thomas .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (51) :17802-17807
[10]   Raman Changes Induced by Electrochemical Oxidation of Poly(triarylamine)s: Toward a Relationship between Molecular Structure Modifications and Charge Generation [J].
Cervantes, Thiago ;
Louarn, Guy ;
de Santana, Henrique ;
Skorka, Lukasz ;
Kulszewicz-Bajer, Irena .
JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (04) :1756-1767
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