An efficient approach to improving fire retardancy and smoke suppression for intumescent flame-retardant polypropylene composites via incorporating organo-modified sepiolite

被引:24
作者
de Juan, Sergio [1 ]
Zhang, Junhao [1 ]
Acuna, Pablo [1 ]
Nie, Shibin [1 ]
Liu, Zhiqi [1 ]
Zhang, Wen [1 ,2 ]
Luisa Puertas, Maria [3 ]
Esteban-Cubillo, Antonio [3 ]
Santaren, Julio [3 ]
Wang, De-Yi [1 ]
机构
[1] IMDEA Mat Inst, C Eric Kandel 2, Madrid 28906, Spain
[2] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Fujian, Peoples R China
[3] Tolsa SA, Res & Dev Dept, Carretera Madrid Rivas Jarama 35, Madrid 28031, Spain
关键词
flame; fire retardancy; mechanical properties; nanoparticles; polymer-matrix composites; MAGNESIUM-HYDROXIDE; SURFACE MODIFICATION; THERMAL-STABILITY; MONTMORILLONITE; NANOCOMPOSITES; FLAMMABILITY; PERFORMANCE;
D O I
10.1002/fam.2757
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work, an efficient approach to improving the fire retardancy and smoke suppression for intumescent flame-retardant polypropylene (PP) composites is developed via incorporating functionalized sepiolite (organo-modified sepiolite [ONSep]). The PP composites with different amounts of intumescent flame retardants and ONSep were prepared by melt compounding. The morphology, thermal behavior, fire retardancy, smoke suppression, and mechanical property of flame-retardant PP composites were studied. The results indicate an appropriate amount of ONSep in the flame-retardant PP composites can increase thermal degradation temperature and char formation as well as a reduction of the peak heat release rate and total heat release; moreover, the addition of ONSep significantly decreases the CO production, total smoke production, smoke production rate, and smoke temperature. Simultaneously, the impact strength of intumescent flame-retardant PP composite is also maintained by introducing an appropriate amount of ONSep as compared with that without ONSep.
引用
收藏
页码:961 / 970
页数:10
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