A FeCl2-graphite sandwich composite with Cl doping in graphite layers: a new anode material for high-performance Li-ion batteries

被引:46
作者
Wang, Lili
Guo, Cong
Zhu, Yongchun [1 ]
Zhou, Jianbin
Fan, Long
Qian, Yitai
机构
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
关键词
DOPED GRAPHENE; CARBON; CHLORINATION; NANOSHEETS; ELECTRODE; CAPACITY; CHLORIDE;
D O I
10.1039/c4nr05070c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A composite with FeCl2 nanocrystals sandwiched between Cl-doped graphite layers has been created via a space-confined nanoreactor strategy. This composite can be used as a new type of anode material for Li-ion batteries, which exhibit high reversible capacity and superior rate capability with excellent cycle life.
引用
收藏
页码:14174 / 14179
页数:6
相关论文
共 32 条
[1]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[2]   Electrochemical properties of nitrogen-doped carbon nanotube anode in Li-ion batteries [J].
Bulusheva, L. G. ;
Okotrub, A. V. ;
Kurenya, A. G. ;
Zhang, Hongkun ;
Zhang, Huijuan ;
Chen, Xiaohong ;
Song, Huaihe .
CARBON, 2011, 49 (12) :4013-4023
[3]   Facile Electrochemical Hydrogenation and Chlorination of Glassy Carbon to Produce Highly Reactive and Uniform Surfaces for Stable Anchoring of Thiolated Molecules [J].
Debela, Ahmed M. ;
Ortiz, Mayreli ;
Beni, Valerio ;
O'Sullivan, Ciara K. .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (25) :7646-7654
[4]   Effect of SOCl2 treatment on electrical and mechanical properties of single-wall carbon nanotube networks [J].
Dettlaff-Weglikowska, U ;
Skákalová, V ;
Graupner, R ;
Jhang, SH ;
Kim, BH ;
Lee, HJ ;
Ley, L ;
Park, YW ;
Berber, S ;
Tománek, D ;
Roth, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (14) :5125-5131
[5]   Investigation of multiplet splitting of Fe 2p XPS spectra and bonding in iron compounds [J].
Grosvenor, AP ;
Kobe, BA ;
Biesinger, MC ;
McIntyre, NS .
SURFACE AND INTERFACE ANALYSIS, 2004, 36 (12) :1564-1574
[6]   An update on the reactivity of nanoparticles Co-based compounds towards Li [J].
Grugeon, S ;
Laruelle, S ;
Dupont, L ;
Tarascon, JM .
SOLID STATE SCIENCES, 2003, 5 (06) :895-904
[7]   Multilayer nanoassembly of Sn-nanopillar arrays sandwiched between graphene layers for high-capacity lithium storage [J].
Ji, Liwen ;
Tan, Zhongkui ;
Kuykendall, Tevye ;
An, Eun Ji ;
Fu, Yanbao ;
Battaglia, Vincent ;
Zhang, Yuegang .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3611-3616
[8]   Lithium Storage ion Carbon Nanostructures [J].
Kaskhedikar, Nitin A. ;
Maier, Joachim .
ADVANCED MATERIALS, 2009, 21 (25-26) :2664-2680
[9]   Chlorination of Reduced Graphene Oxide Enhances the Dielectric Constant of Reduced Graphene Oxide/Polymer Composites [J].
Kim, Jin-Young ;
Lee, Wi Hyoung ;
Suk, Ji Won ;
Potts, Jeffrey R. ;
Chou, Harry ;
Kholmanov, Iskandar N. ;
Piner, Richard D. ;
Lee, Jongho ;
Akinwande, Deji ;
Ruoff, Rodney S. .
ADVANCED MATERIALS, 2013, 25 (16) :2308-2313
[10]   Photochemical Chlorination of Graphene [J].
Li, Bo ;
Zhou, Lin ;
Wu, Di ;
Peng, Hailin ;
Yan, Kai ;
Zhou, Yu ;
Liu, Zhongfan .
ACS NANO, 2011, 5 (07) :5957-5961