Stereochemistry of lead(II) complexes containing sulfur and selenium donor atom ligands

被引：91

作者：

Davidovich, Ruven L. ^{[1
]}

Stavila, Vitalie ^{[2
]}

Whitmire, Kenton H. ^{[3
]}

机构：

[1] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia

[2] Sandia Natl Labs, Livermore, CA 94550 USA

[3] Rice Univ, Dept Chem, Houston, TX 77005 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2010年 / 254卷 / 17-18期

基金：

美国国家科学基金会;

关键词：

Lead; Sulfur; Selenium; VSEPR; Stereochemically active; Lone pair; THIOUREA COORDINATION-COMPLEXES; GROUP METAL-CATIONS; SINGLE-SOURCE PRECURSORS; RAY CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; PB(II) SALTS; SUPRAMOLECULAR ASSOCIATIONS; STRUCTURAL-CHARACTERIZATION; CHEMISTRY; PB;

D O I：

10.1016/j.ccr.2010.05.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stereochemistry of lead(II) complexes with S- and Se-donor atom ligands, including mixed ligand complexes is reviewed with respect to the geometry of the first coordination sphere of the Pb(II) atom in these compounds and rationalized in terms of the valence shell electron-pair repulsion (VSEPR) model. The most comprehensively structurally characterized classes of lead(II) thio and seleno complexes are discussed, including monothio-, dithio(seleno)-, trithio- and tetrathio-complexes, as well as Pb(II) dialkyldithio(seleno)carbamates, alkylxanthates and dialkyl(aryl) phosphorodithio(seleno)lates. Data about the polyhedral shape of the primary coordination sphere, coordination number (CN), bond lengths (primary and secondary) and bond angles of the Pb(II) atom in the compounds under investigation are systematized in comprehensive tables. The particularities of the stereochemistry of Pb(II) complexes with S(Se)-donor atom ligands are comparatively discussed with the stereochemistry of lead(II) complexes with oxygen donor ligands. (c) 2010 Elsevier B.V. All rights reserved.

引用

页码：2193 / 2226

页数：34

共 123 条

[1] The molecular and solid state structure of lead thiobenzoate Pb[SC(O)Ph]2 [J].

Adams, Richard D. ;

Zhu, Lei .

JOURNAL OF MOLECULAR STRUCTURE, 2008, 890 (1-3) :130-132

[2] Growth of lead chalcogenide thin films using single-source precursors [J].

Afzaal, M ;

Ellwood, K ;

Pickett, NL ;

O'Brien, P ;

Raftery, J ;

Waters, J .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (08) :1310-1315

[3]

Alcock N. W., 1972, Adv. Inorg. Chem. Radiochem, V15, P1, DOI [DOI 10.1016/S0065-2792(08)60016-3, 10.1016/S0065-2792(08)60016-3]

[4]

[Anonymous], 2006, LEAD CHEM ANAL ASPEC

[5] Monomeric, one- and two-dimensional networks incorporating (2,6-Me2C6H3S)2Pb building blocks [J].

Appleton, SE ;

Briand, GG ;

Decken, A ;

Smith, AS .

DALTON TRANSACTIONS, 2004, (21) :3515-3520

[6] Bis(N-cyclohexyl-N-ethyldithiocarbamato-S,S′)lead(II) [J].

Baba, I ;

Farina, Y ;

Othman, AH ;

Razak, IA ;

Fun, HK ;

Ng, SW .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 :M35-M36

[7] Lessons from zinc-binding peptides [J].

Berg, JM ;

Godwin, HA .

ANNUAL REVIEW OF BIOPHYSICS AND BIOMOLECULAR STRUCTURE, 1997, 26 :357-371

[8] STRUCTURE OF A NOVEL NEUTRAL LEAD(II) COMPLEX WITH DIPROPYLDITHIOCARBAMATE [J].

BHARADWAJ, PK ;

ARBUCKLE, BW ;

MUSKER, WK .

INORGANICA CHIMICA ACTA, 1988, 142 (02) :243-246

[9] Two-dimensional network acquired by Pb(II)-2-aminoethanethiolate [J].

Bharara, Mohan S. ;

Parkin, Sean ;

Atwood, David A. .

INORGANICA CHIMICA ACTA, 2006, 359 (10) :3375-3378

[10] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

← 1 2 3 4 5 6 7 8 9 10 →