Kinetic studies for Ni(II) biosorption from industrial wastewater by Cassia fistula (Golden Shower) biomass

The present study explores the ability of Cassia fistula waste biomass to remove Ni(II) from industrial effluents. C.fistula biomass was found very effective for Ni(II) removal from wastewater of Ghee Industry (GI), Nickel Chrome Plating Industry (Ni-Cr PI), Battery Manufacturing Industry (BMI), Tanner Industry: Lower Heat Unit (TILHU), Tannery Industry: Higher Heat Unit (TIHHU), Textile Industry: Dying Unit (TIDU) and Textile Industry: Finishing Unit (TIFU). The initial Ni(II) concentration in industrial effluents was found to be 34.89 +/- 0.01, 183.56 +/- 0.08, 21.19 +/- 0.01, 43.29 +/- 0.03, 47.26 +/- 0.02, 31.38 +/- 0.01 and 31,09 0.01 mg/L in GI, Ni-Cr PI, BMI, TILHU, TIHHU, TIDU and TIFU, respectively. After biosorption the final Ni(II) concentration in industrial effluents was found to be 0.05 +/- 0.01, 17.26 +/- 0.08, 0.03 0.01, 0.05 +/- 0.01, 0.1 +/- 0.01, 0.07 +/- 0.01 and 0.06 +/- 0.01 mg/L in GI, Ni-Cr PI, BMI, TILHU, TIHHU, TIDU and TIFU, respectively. The % sorption Ni(11) ability of C. fistula from seven industries included in present study tend to be in following order: TILHU (99.88) > GI (99.85) approximate to BMI (99.85) > TIFU (99.80) > TIHHU (99.78) > TIDU (99.77) >> Ni-Cr PI (90.59). Sorption kinetic experiments were performed in order to investigate proper sorption time for Ni(II) removal from wastewater. Batch metal ion uptake capacity experiments indicated that sorption equilibrium reached much faster in case of industrial wastewater samples (480 min) in comparison to synthetic wastewater (1440 min) using same biosorbent. The kinetic data were analyzed in term of pseudo-first-order and pseudo-second-order expressions. Pseudo-second-order model described well the sorption kinetics of Ni(II) onto C. fistula biomass from industrial effluents in comparison to pseudo-first-order kinetic model. Due to unique high Ni(II) sorption capacity of C. fistula waste biomass it can be concluded that it is an excellent. biosorbent for Ni(II) uptake from industrial effluents. (c) 2007 Elsevier B.V All rights reserved.