Supramolecular Interactions Involved in the Solid State Structure of N,N′-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine

被引：8
|
作者：
El-Qisairi, Arab K. [1 ]
Qaseer, Hanan A. [1 ]
Alshahateet, Solhe F. [1 ]
Qaseer, M. K. Hasan [2 ]
Zaghal, Mukarram H. [3 ]
Al-Btoush, Wa'el [1 ]
Dawe, Louise N. [4 ]
机构：
[1] Mutah Univ, Fac Sci, Dept Chem, Mutah 61710, Jordan
[2] Jordan Univ Sci & Technol, Fac Sci, Dept Phys, Irbid, Jordan
[3] Yarmouk Univ, Dept Chem, Fac Sci, Irbid, Jordan
[4] Mem Univ Newfoundland, Ctr Chem Anal Res & Training, St John, NF A1B 3X7, Canada
来源：
CROATICA CHEMICA ACTA | 2014年 / 87卷 / 02期
关键词：
centrosymmetric dimer interactions; unit cell packing arrangement; spectral properties; high Z-value structure; CADMIUM(II) SCHIFF-BASE; PLATINUM(II) COMPLEXES; CRYSTAL-STRUCTURES; METAL-COMPLEXES; HYDROGEN-BOND; LIGANDS; PALLADIUM(II); CYCLOHEXENE; DERIVATIVES; NICKEL(II);
D O I：
10.5562/cca2289
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structure of the symmetrical Schiff base, N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine (bpfd) has been characterized by single crystal X-ray diffraction. The non-covalent supramolecular chemistry involved in the crystal structure of this ligand has been carefully investigated. The structure adopted different motifs of nitrogen-hydrogen interactions that led to the formation of centrosymmetric dimers. In addition, edge-edge and face-face nitrogen-nitrogen interactions were observed and reported. The Schiff base (bpfd) ligand crystallizes in a monoclinic space group C12/cl with a = 19.128(2) angstrom; b = 5.8776(6) angstrom; c = 13.1403(15) angstrom; alpha = 90 degrees; beta = 121.970 degrees (4); gamma = 90 degrees and z = 4. This structure is an example of compounds with many symmetry-independent molecules in the asymmetric unit cell (Z > 2).
引用
收藏
页码：123 / 128
页数：6
相关论文
共 50 条
  • [1] Bis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate)
    Wang, Chen-Yi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1038 - U394
  • [2] N,N′-Bis(2-aminobenzyl)ethane-1,2-diamine
    de Barbarin, Cecilia Rodriguez
    Bernes, Sylvain
    Najera, Blanca
    Elizondo, Perla
    Cerda, Patricia
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O549 - O550
  • [3] N,N′-bis(2-thienylmethylene)ethane-1,2-diamine
    Wang, Da-Qi
    Wang, Qiang
    Xiao, Li-Jun
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4865 - U6525
  • [4] N,N'-bis(2-iodobenzylidene)ethane-1,2-diamine
    Fun, Hoong-Kun
    Kia, Reza
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1870 - U3288
  • [5] [N,N-Bis(2-aminoethyl)ethane-1,2-diamine](ethane-1,2-diamine)nickel(II) thiosulfate trihydrate
    Seidlhofer, Beatrix
    Nather, Christian
    Bensch, Wolfgang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M167 - U826
  • [6] [μ-N,N′-Bis(2-pyridylmethylene)ethane-1,2-diamine]bis{aqua[N,N′-bis(2-pyridylmethylene)ethane-1,2-diamine]manganese(II)} tetrakis(perchlorate)
    Ha, Kwang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M255 - U3139
  • [7] N,N′-Bis[1-(thiophen-2-yl)ethylidene]ethane-1,2-diamine
    Asiri, Abdullah M.
    Al-Youbi, Abdulrahman O.
    Faidallah, Hassan M.
    Alamry, Khalid A.
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2465 - U1465
  • [8] N,N′-Bis(2,3-dimethoxybenzylidene)ethane-1,2-diamine
    Xue, Hua
    Li, Wenjuan
    Han, Hongfei
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2431 - U1148
  • [9] N,N′-bis[(E)-2-benzylidenepropylidene]ethane-1,2-diamine
    Khalaji, Aliakbar Dehno
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1771 - U2078
  • [10] N,N′-bis(5-chlorosalicylidene)ethane-1,2-diamine
    Kubono, K
    Kushida, K
    Yokoi, K
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : O1383 - O1384
12345