Ir(iii)-catalyzed thioether directed arene C-H alkenylation

被引：14

作者：

Li, Chen ^{[1
]}

Chen, Xian ^{[1
]}

Bao, Rui-Peng ^{[2
]}

Li, Dong-Li ^{[1
]}

Zhang, Kun ^{[1
]}

Wang, Dong-Hui ^{[2
]}

机构：

[1] Wuyi Univ, Sch Biotechnol & Hlth Sci, 22 Dangcheng Vill, Jiangmen 529020, Guangdong, Peoples R China

[2] Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, CAS Key Lab Synthet & Self Assembly Chem Organ Fu, 345 Linngling Rd, Shanghai 200032, Peoples R China

来源：

RSC ADVANCES | 2019年 / 9卷 / 52期

基金：

国家重点研发计划;

关键词：

BENZYL THIOETHERS; SULFUR; FUNCTIONALIZATION; ARYLATION; ACTIVATION; SULFOXIDES; DERIVATIVES; OLEFINATION; AMIDATION;

D O I：

10.1039/c9ra06811b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, we demonstrate an Ir(iii)-catalyzed thioether directed alkenylation of arene C-H bonds under mild reaction conditions. The selectivity for mono- or di-alkenylation is controlled by the concentration of alkene and oxidant loading. Various functional groups are tolerated, and moderate to good yields of alkenylated products are achieved.

引用

页码：30134 / 30138

页数：5

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