Advances in chemistry of hydrogen bis(fluorosulfonyl)imide and its derivatives

被引：6

作者：

Singh, Rajendra P. ^{[1
]}

Hu, Qichao ^{[1
]}

机构：

[1] SolidEnergy Syst LLC, 35B Cabot Rd, Woburn, MA 01801 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2019年 / 226卷

关键词：

Hydrogen bis(fluorosulfonyl)imide; Ionic liquids; Metallic salts; Eutectic mixture; Electronics; IONIC LIQUID ELECTROLYTES; LOW-MELTING TEMPERATURES; ALKALI BIS(FLUOROSULFONYL)AMIDES; ELECTROCHEMICAL PROPERTIES; FLUORINE CARRIERS; CRYSTAL-STRUCTURE; METAL-ELECTRODES; GREEN SOLVENTS; MOLTEN-SALT; MIXTURES;

D O I：

10.1016/j.jfluchem.2019.05.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review is devoted to the chemistry of hydrogen bis(fluorosulfonyl)imide (HFSI) and its derivatives. HFSI is a valuable fluorine containing compound and in recent years, the interests in HFSI have been concentrated on the preparation of its metallic salts, ionic liquids, eutectic mixtures, which are used in electronics. HFSI is a colorless liquid, m.p. 17 degrees C, b.p. 170 degrees C, density 1.89 g/cm(3). HFSI is a strong acid with pK(a) = 1.28 (water). It is very soluble in water and in various organic solvents such as dichloromethane, chloroform, dimethylcarbonate, acetonitrile, ethyl acetate. Hydrolysis in water is relatively very slow at low temperature. Herein, advances in chemistry of hydrogen bis(fluorosulfonyl)imide and its derivatives, the literatures details of past two decades have been summarized with the aim of having useful literature information to the scientific community.

引用

页数：12

共 79 条

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