Copper-catalyzed enantioselective propargylic substitution of propargylic acetates with enamines

被引：18
|
作者：
Wang, Bo [1 ,2 ]
Liu, Chunxiao [1 ]
Guo, Hongchao [2 ]
机构：
[1] Guizhou Univ, State Key Lab Breeding Base Green Pesticide & Agr, Key Lab Green Pesticide & Agr Bioengn, Minist Educ, Guiyang 550025, Peoples R China
[2] China Agr Univ, Dept Appl Chem, Beijing 100193, Peoples R China
来源：
RSC ADVANCES | 2014年 / 4卷 / 95期
关键词：
ASYMMETRIC ALLYLIC ALKYLATION; ALLENYLIDENE COMPLEXES; BETA-KETOESTERS; ALCOHOLS; ESTERS; AMINATION; CHEMISTRY; LIGANDS; CATIONS; AMINES;
D O I：
10.1039/c4ra09431j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
With the use of chiral tridentate P,N,N ligand, copper-catalyzed enantioselective propargylic substitution of propargylic acetates with enamines has been achieved, giving the corresponding propargylic ketones in high yields and with excellent enantioselectivities.
引用
收藏
页码：53216 / 53219
页数：4
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