Bis(pyridine)iodonium(I) tetrafluoroborate

被引：27
作者：
Alvarez-Rúa, C
García-Granda, S
Ballesteros, A
González-Bobes, F
González, JM
机构：
[1] Univ Oviedo, Dept Quim Fis & Analit, E-33006 Oviedo, Spain
[2] Univ Oviedo, Inst Univ Quim Organomet Enrique Moles, Unidad Asociada CSIC, E-33071 Oviedo, Spain
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷
关键词：
D O I：
10.1107/S1600536802020639
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C10H10IN2+.BF4-, or IPy2BF4, is found to crystallize in the monoclinic crystal system. The asymmetric unit contains two tetrafluoroborate anions, one independent IPy2 cation and two half-cations; for the latter the I atoms lie on centres of symmetry. A slight deviation from planarity is observed in the crystallographically independent IPy2 cation.
引用
收藏
页码：O1381 / O1383
页数：3
相关论文
共 10 条
[1]   SIR92 - a program for automatic solution of crystal structures by direct methods [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, G ;
GUAGLIARDI, A ;
BURLA, MC ;
POLIDORI, G ;
CAMALLI, M .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435
[2]   I(PY)2BF4, A NEW REAGENT IN ORGANIC-SYNTHESIS - GENERAL-METHOD FOR THE 1,2-IODOFUNCTIONALIZATION OF OLEFINS [J].
BARLUENGA, J ;
GONZALEZ, JM ;
CAMPOS, PJ ;
ASENSIO, G .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (04) :319-320
[3]   Transferring iodine: more than a simple functional group exchange in organic synthesis [J].
Barluenga, J .
PURE AND APPLIED CHEMISTRY, 1999, 71 (03) :431-436
[4]   A CHARGE-TRANSFER COMPLEX - BIS(2,4,6-TRIMETHYL-1-PYRIDYL)IODONIUM PERCHLORATE [J].
BRAYER, GD ;
JAMES, MNG .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (FEB) :654-657
[5]   STRUCTURE OF SOLID COMPOUND FORMED BY ADDITIONOF .2. MOLECULES OF IODINE TO .1. MOLECULE OF PYRIDINE [J].
HASSEL, O ;
HOPE, H .
ACTA CHEMICA SCANDINAVICA, 1961, 15 (02) :407-&
[6]  
*NON BV, 1997, COLLECT
[7]   Processing of X-ray diffraction data collected in oscillation mode [J].
Otwinowski, Z ;
Minor, W .
MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 :307-326
[8]   XABS2 - AN EMPIRICAL ABSORPTION CORRECTION PROGRAM [J].
PARKIN, S ;
MOEZZI, B ;
HOPE, H .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1995, 28 :53-56
[9]  
Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]
[10]  
Spek A.L., 2001, PLATON MULTIPURPOSE
1