Donor-Acceptor [2]- and [3]Catenanes Assembled from Versatile Pre-Organized Cp*Rh/Ir-Directed Pseudorotaxane Tectons

被引：19
作者：
Liu, Dong [1 ]
Lu, Ye [1 ]
Lin, Yue-Jian [1 ]
Jin, Guo-Xin [1 ,2 ]
机构：
[1] Fudan Univ, Collaborat Innovat Ctr Chem Energy Mat, Dept Chem, State Key Lab Mol Engn Polymers, 2005 Songhu Rd, Shanghai 200438, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2019年 / 25卷 / 65期
基金：
美国国家科学基金会;
关键词：
catenanes; crown compounds; donor-acceptor interactions; self-assembly; supramolecular chemistry; SELECTIVE SYNTHESIS; CATENATION;
D O I：
10.1002/chem.201904082
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A stepwise self-assembly protocol has been used to synthesize [2]- and [3]catenanes. Firstly, binuclear Cp*Rh/Ir-directed (Cp*=pentamethylcyclopentadienyl) pseudorotaxanes were prepared through self-assembly, driven by donor-acceptor interactions between electron-deficient naphthalenediimide (NDI) units and an electron-rich crown ether. Subsequently, the pre-organized pseudorotaxanes were applied as tectons for self-assembly of [2]- and [3]catenanes by combination with very simple linkers. The structures of the catenanes were confirmed by NMR spectroscopy, ESI mass spectrometry, single-crystal X-ray diffraction analysis, and elemental analysis.
引用
收藏
页码：14785 / 14789
页数：5
相关论文
共 40 条
[1]   Catenation and encapsulation induce distinct reconstitutions within a dynamic library of mixed-ligand Zn4L6 cages [J].
Black, Samuel P. ;
Wood, Daniel M. ;
Schwarz, Felix B. ;
Ronson, Tanya K. ;
Holstein, Julian J. ;
Stefankiewicz, Artur R. ;
Schalley, Christoph A. ;
Sanders, Jeremy. K. M. ;
Nitschke, Jonathan R. .
CHEMICAL SCIENCE, 2016, 7 (04) :2614-2620
[2]   Molecular catenation via metal-directed self-assembly and π-donor/π-acceptor interactions:: Efficient one-pot synthesis, characterization, and crystal structures of [3]catenanes based on Pd or Pt dinuclear metallocycles [J].
Blanco, Victor ;
Chas, Marcos ;
Abella, Dolores ;
Peinador, Carlos ;
Quintela, Jose M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (45) :13978-13986
[3]   Self-assembly of new fluorescent Pd(II) and Pt(II) 2,7-diazapyrenium-based metallocycles and study of their inclusion complexes and [3]catenanes [J].
Blanco, Victor ;
Garcia, Marcos D. ;
Peinador, Carlos ;
Quintela, Jose M. .
CHEMICAL SCIENCE, 2011, 2 (12) :2407-2416
[4]   Regioselective Catenation-of Dinuclear Palladium and Platinum Metallocycles Promoted by π•••π Interactions [J].
Blanco, Victor ;
Abella, Dolores ;
Pia, Elena ;
Platas-Iglesias, Carlos ;
Peinador, Carlos ;
Quintela, Jose M. .
INORGANIC CHEMISTRY, 2009, 48 (09) :4098-4107
[5]   Probing Donor-Acceptor Interactions and Co-Conformational Changes in Redox Active Desymmetrized [2]Catenanes [J].
Cao, Dennis ;
Amelia, Matteo ;
Klivansky, Liana M. ;
Koshkakaryan, Gayane ;
Khan, Saeed I. ;
Semeraro, Monica ;
Silvi, Serena ;
Venturi, Margherita ;
Credi, Alberto ;
Liu, Yi .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (03) :1110-1122
[6]   Synthesis of [3]catenanes based on metal-directed self-assembly and π-donor/π-acceptor interactions [J].
Chas, Marcos ;
Blanco, Victor ;
Peinador, Carlos ;
Quintela, Jose M. .
ORGANIC LETTERS, 2007, 9 (04) :675-678
[7]   New hybrid [2]catenanes based on a 4,4′-bipyridinium ligand [J].
Chas, Marcos ;
Pia, Elena ;
Toba, Rosa ;
Peinador, Carlos ;
Quintela, Jose M. .
INORGANIC CHEMISTRY, 2006, 45 (16) :6117-6119
[8]   A [2]catenane-based solid state electronically reconfigurable switch [J].
Collier, CP ;
Mattersteig, G ;
Wong, EW ;
Luo, Y ;
Beverly, K ;
Sampaio, J ;
Raymo, FM ;
Stoddart, JF ;
Heath, JR .
SCIENCE, 2000, 289 (5482) :1172-1175
[9]   Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination [J].
Cook, Timothy R. ;
Stang, Peter J. .
CHEMICAL REVIEWS, 2015, 115 (15) :7001-7045
[10]  
Cougnon F. B. L., 2012, ANGEW CHEM, V124, P1472
1234