Two Coordination Polymers Based on Pamoic Acid and (1,4-Bis(imidazol-1-yl)-butane: Synthesis, Structures and Properties

被引：0

作者：

Tu Chang-Zheng ^{[1
]}

Yang Yu-Ting ^{[1
]}

Wang Fan ^{[1
]}

Wang Jian-Ling ^{[1
]}

Yin Hong-Ju ^{[1
]}

Cheng Fei-Xiang ^{[1
]}

机构：

[1] Qujing Normal Univ, Coll Chem & Environm Sci, Qujing 655011, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2021年 / 40卷 / 04期

基金：

中国国家自然科学基金;

关键词：

crystal structures; pamoic acid; luminescence; magnetic properties; METAL-ORGANIC FRAMEWORK; MAGNETIC-PROPERTIES; LIGANDS; ARCHITECTURES; COMPLEXES; MOLECULE; IONS;

D O I：

10.14102/j.cnki.0254-5861.2011-2946

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two mixed-ligand compounds, namely [Mn-2(bimb)(PA)(2)](n) (1) and [Zn(bimb)(PA)](n) (2) (H(2)PA = pamoic acid, bimb = 1,4-bis(imidazol-1-yl)-butane) have been synthesized under the same solvothermal conditions. Compound 1 can be described as (4,4) topology based on the 4-connected [Mn-2(COO)(4)] paddle-wheel units, which contains both rotaxane- and catenane-like motifs. For 2, the 2D wavy-like network interlocked with each other and resulted in a 2-fold interpenetrated 2D -> 3D architecture. The structural differences of the two compounds are mainly due to the differences of metal ions and coordination modes of the PA(2-) ligand. In addition, the magnetism and photoluminescent properties of them have also been explored.

引用

页码：473 / 481

页数：9

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