Epoxides and Aziridines from α, β-Unsaturated Aldehydes

被引：4

作者：

Vchislo, Nadezhda V. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, 1 Favorsky St, Irkutsk 664033, Russia

来源：

MINI-REVIEWS IN ORGANIC CHEMISTRY | 2017年 / 14卷 / 03期

关键词：

alpha; beta-Uunsaturated aldehydes; epoxides; aziridines; asymmetric organocatalysis; biologically active compound; ORGANOCATALYTIC ASYMMETRIC EPOXIDATION; ALPHA; BETA-UNSATURATED ALDEHYDES; ENANTIOSELECTIVE AZIRIDINATION; SUBSTITUTED ACROLEINS; HYDROGEN-PEROXIDE; CATALYSTS; SCOPE; LIGANDS; ENALS;

D O I：

10.2174/1570193X14666170206114541

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Epoxides and aziridines are very useful small heterocycles. The synthesis of these three-membered heterocycles including those derived from a, a-unsaturated aldehydes is a dynamic area of research. Among numerous approaches to construction of three-membered cycles with O- or N-heteroatoms are metallo-and organocatalysis. This review summarizes and highlights the methods for the synthesis of epoxides and aziridines via transformations of alpha, beta-enals, which have been developed over the last 10 years.

引用

页码：197 / 203

页数：7

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