Generation and intramolecular reactivity of acyl radicals from alkynylthiol esters under reducing tin-free conditions

被引：78
|
作者：
Benati, L
Calestani, G
Leardini, R
Minozzi, M
Nanni, D
Spagnolo, P
Strazzari, S
机构：
[1] Univ Bologna, Dipartimento Chim Organ A Mangini, I-40136 Bologna, Italy
[2] Univ Parma, Dipartimento Chim Gen & Inorgan Analit & Chim Fis, I-43100 Parma, Italy
来源：
ORGANIC LETTERS | 2003年 / 5卷 / 08期
关键词：
D O I：
10.1021/ol034252r
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The radical chain reaction of benzenethiol with alkynylthiol esters provides a new, valuable protocol for the tin-free generation of acyl radicals that arise from intramolecular substitution at sulfur by the initial sulfanylvinyl radicals.
引用
收藏
页码：1313 / 1316
页数：4
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