Solvent-free synthesis of C9 and C10 branched alkanes with furfural and 3-pentanone from lignocellulose

被引：37
作者：
Chen, Fang [1 ,2 ]
Li, Ning [1 ]
Li, Shanshan [1 ,2 ]
Yang, Jinfan [1 ,2 ]
Liu, Fei [1 ]
Wang, Wentao [1 ]
Wang, Aiqin [1 ]
Cong, Yu [1 ]
Wang, Xiaodong [1 ]
Zhang, Tao [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2015年 / 59卷
基金：
中国国家自然科学基金;
关键词：
Aldol condensation; Hydrodeoxygenation; Lignocellulose; Jet fuel; Branched alkane; FUEL RANGE ALKANES; LIQUID ALKANES; LACTIC-ACID; BIOMASS; JET; CONVERSION; DIESEL;
D O I：
10.1016/j.catcom.2014.11.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Jet fuel range branched alkanes were first synthesized under solvent-free conditions by the aldol condensation of furfural and 3-pentanone from lignocellulose followed by the one-step hydrodeoxygenation (HDO). Among the investigated solid base catalysts, CaO and KF/Al2O3 demonstrated the highest activity for the aldol condensation reaction of furfural and 3-pentanone. The aldol condensation product of furfural and 3-pentanone (liquid at room temperature) was directly hydrodeoxygenated to 4-methyl-nonane and 4-methyl-octane. These alkanes have low freezing points (174.1 K and 159.8 K) and can be blended into jet fuel without hydroisomerization. Among the investigated HDO catalysts, the Ni-Cu/SiO2 exhibited the best performance. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：229 / 232
页数：4
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