Photocatalytic oxidation of organic dyes by nano-sized metal molybdate incorporated titanium dioxide (MxMoxTi1-xO6) (M = Ni, Cu, Zn) photocatalysts

被引：75
作者：
Ghorai, T. K.
Dhak, D.
Biswas, S. K.
Dalai, S.
Pramanik, P. [1 ]
机构：
[1] Vidyasagar Univ, Dept Chem & Chem Technol, Midnapore 721102, India
[2] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India
[3] Bajkul Milani Mahavidyalaya, Dept Chem, Bajkul 721655, India
[4] Serampore Coll, Dept Chem, Hooghly 712201, India
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 273卷 / 1-2期
关键词：
metal molybdate; titanium dioxide; nanoparticle; photochemical reaction;
D O I：
10.1016/j.molcata.2007.03.075
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Different metal molybdates incorporated titanium dioxide were prepared by the chemical solution decomposition (CSD) method. Among many transition-metal molybdates, nickel molybdate incorporated titanium dioxide (NMTI) was found to be more photoactive than P25 TiO2 and other metal molybdate doped TiO2 (MxMoxTi1-xO6) (M = Ni, Cu, Zn; x = 0.05), for photocatalytic oxidation of various dyes solution to harmless decolorized solution at room temperature with the help of Hg lamp. The prepared nano powders were characterized by XRD, UV-vis spectra, specific surface area (BET), UV-vis diffuse reflectance spectrum, EPR spectrum and TEM analyses. The average particle size of NMT1 was found to be 15 nm measured from TEM and calculated band gap from adsorption edge is found to be 2.66 eV. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：224 / 229
页数：6
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