Alkyl- or arylthiolation of aryl iodide via cleavage of the S-S bond of disulfide compound by nickel catalyst and zinc

被引：216

作者：

Taniguchi, N ^{[1
]}

机构：

[1] Fukushima Med Univ, Dept Chem, Fukushima 9601295, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 20期

关键词：

D O I：

10.1021/jo040184q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various aryl sulfides can be synthesized by nickel-catalyzed alkyl- or arylthiolation of aryl iodide with a disulfide compound. This reaction produces Ni(0) from NiBr2-bpy by the reduction with zinc, and this generated complex works as an activating species to convert ArI into ArSR under neutral conditions. Furthermore, this system enables the use of two RS groups in (RS)(2).

引用

页码：6904 / 6906

页数：3

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