Temperature dependence of the pre-edge structure in the Ti K-edge x-ray absorption spectrum of rutile

被引：20
作者：
Durmeyer, O. [1 ]
Beaurepaire, E. [1 ]
Kappler, J-P [1 ]
Brouder, Ch [2 ,3 ]
Baudelet, F. [4 ]
机构：
[1] CNRS, UMR 7504, ULP, IPCMS, F-67034 Strasbourg 2, France
[2] Univ Paris 06, CNRS, UMR 7590, Inst Mineral & Phys Milieux Condenses,IPGP, F-75015 Paris, France
[3] Univ Paris 07, CNRS, UMR 7590, Inst Mineral & Phys Milieux Condenses,IPGP, F-75015 Paris, France
[4] Synchrotron SOLEIL, F-91192 Gif Sur Yvette, France
来源：
JOURNAL OF PHYSICS-CONDENSED MATTER | 2010年 / 22卷 / 12期
关键词：
TRANSITION-METAL COMPOUNDS; VIBRATIONAL FINE-STRUCTURE; DEBYE-WALLER FACTORS; LATTICE-DYNAMICS; ATOMIC-STRUCTURE; LOCAL-STRUCTURE; NEUTRON-DIFFRACTION; ELECTRONIC-SPECTRA; PHASE-TRANSITIONS; POLARIZED XAFS;
D O I：
10.1088/0953-8984/22/12/125504
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
The temperature dependence of the pre-edge features in x-ray absorption spectroscopy is reviewed. Then, the temperature dependence of the pre-edge structure at the K-edge of titanium in rutile TiO2 is measured at low and room temperature. The first two peaks grow with temperature. The fact that these two peaks also correspond to electric quadrupole transitions is explained by a recently proposed theory.
引用
收藏
页数：6
相关论文
共 72 条
[1]  
Ankudinov AL, 2005, PHYS SCRIPTA, VT115, P24
[2]  
Arai H, 2007, AIP CONF PROC, V882, P108
[3]  
Arfaoui M, 2007, AIP CONF PROC, V882, P331
[4]   Calculation of multipole transitions at the FeK pre-edge through p-d hybridization in the Ligand Field Multiplet model [J].
Arrio, MA ;
Rossano, S ;
Brouder, C ;
Galoisy, L ;
Calas, G .
EUROPHYSICS LETTERS, 2000, 51 (04) :454-460
[5]   Temperature dependent changes of the Mn 3d and 4p bands near Tc in colossal magnetoresistance systems:: XANES study of La1-xCaxMnO3 [J].
Bridges, F ;
Booth, CH ;
Kwei, GH ;
Neumeier, JJ ;
Sawatzky, GA .
PHYSICAL REVIEW B, 2000, 61 (14) :R9237-R9240
[6]   INFLUENCE OF ATOMIC DISPLACEMENTS ON XAFS [J].
BROUDER, C ;
GOULON, J .
PHYSICA B, 1989, 158 (1-3) :351-354
[7]  
BROUDER C, 1992, MATER RES SOC SYMP P, V253, P411
[8]  
BROUDER C, 1990, C P SIF BOLOGNA, V25, P19
[9]  
BROUDER C, 2009, ARXIV09120792
[10]  
BROUDER C, 2010, PHYS REV B IN PRESS
12345678