Bio-based one-component epoxy resin: Novel high-performance anticorrosive coating from agro-industrial byproduct

被引：16

作者：

Silva, Lucas R. R. da ^{[1
]}

Carvalho, Bruna A. ^{[2
]}

Pereira, Rita C. S. ^{[2
]}

Diogenes, Otilio B. F. ^{[1
]}

Pereira, Ursula C. ^{[1
]}

Silva, Kassia T. da ^{[1
]}

Araujo, Walney S. ^{[1
]}

Mazzetto, Selma E. ^{[2
]}

Lomonaco, Diego ^{[2
]}

机构：

[1] Univ Fed Ceara, Dept Met & Mat Engn, BR-60440900 Fortaleza, CE, Brazil

[2] Univ Fed Ceara, Dept Organ & Inorgan Chem, BR-60440900 Fortaleza, CE, Brazil

来源：

PROGRESS IN ORGANIC COATINGS | 2022年 / 167卷

关键词：

Organic coating; EIS; Corrosion protection; Bio-based coatings; CASHEW NUT SHELL; MECHANICAL-PROPERTIES; ORGANIC COATINGS; VEGETABLE-OILS; CARDANOL; ACID; NETWORKS; PROPERTY;

D O I：

10.1016/j.porgcoat.2022.106861

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this present work, an epoxy resin produced from an agroindustrial byproduct, cashew nutshell liquid (CNSL), was used for manufacturing a one-component anticorrosive epoxy coating. CNSL-based epoxy resin (e-CNSL) was synthesized using a solvent-free methodology with performic acid generated in situ. The chemical structure of resin was evaluated by FTIR and H-1 NMR. The curing parameters of the epoxy-phenol system with 1-methylimidazole (1-MIM) as an accelerator were investigated by differential scanning calorimetry (DSC). The use of only 5% by weight of 1-MIM was efficient to catalyze the reaction, obtaining the lowest cure temperature (150 degrees C). The coating showed high crosslinking and good thermal-mechanical performance, where the initial decomposition temperature was 200 degrees C and glass transition temperature was 30 degrees C. The anti-corrosive performance of e-CNSL/MIM5 exposed to salt spray and 3.5% w/v NaCl solution was monitored by electrochemical impedance spectroscopy, adhesion, and visual evaluation during the exposure period. Humidity test with visual evaluation was also performed. The coating presented high impedance module at 10(8) Omega.cm(2) and high adhesive property, suffering low delamination during the tests. Thus, the one-component bio-based coating developed is promising to be applied for corrosion protection purposes.

引用

页数：12

共 56 条

[1] Epoxidation of Tall Oil Catalyzed by an Ion Exchange Resin under Conventional Heating and Microwave Irradiation [J].

Aguilera, Adriana Freites ;

Rahkila, Jani ;

Hemming, Jarl ;

Nurmi, Maristiina ;

Torres, Gaetan ;

Razat, Theophile ;

Tolvanen, Pasi ;

Eranen, Kari ;

Leveneur, Sebastien ;

Salmi, Tapio .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2020, 59 (22) :10397-10406

[2] Another approach for ranking and evaluating organic paint coatings via electrochemical impedance spectroscopy [J].

Akbarinezhad, E. ;

Bahremandi, M. ;

Faridi, H. R. ;

Rezaei, F. .

CORROSION SCIENCE, 2009, 51 (02) :356-363

[3] Application of electrochemical impedance spectroscopy to study the degradation of polymer-coated metals [J].

Amirudin, A ;

Thierry, D .

PROGRESS IN ORGANIC COATINGS, 1995, 26 (01) :1-28

[4] Development of fully organic coating system modified with epoxidized soybean oil with superior corrosion protection performance [J].

Ammar, S. ;

Iling, A. W. M. ;

Ramesh, K. ;

Ramesh, S. .

PROGRESS IN ORGANIC COATINGS, 2020, 140

[5] Preparation of green cardanol-based epoxy and hardener as primer coatings for petroleum and gas steel in marine environment [J].

Atta, Ayman M. ;

Al-Hodan, Hamad A. ;

Hameed, Reda S. Abdel ;

Ezzat, Abdelrahman O. .

PROGRESS IN ORGANIC COATINGS, 2017, 111 :283-293

[6] Non-endocrine disruptor effect for cardanol based plasticizer [J].

Briou, Benoit ;

Caillol, Sylvain ;

Robin, Jean-Jacques ;

Lapinte, Vincent .

INDUSTRIAL CROPS AND PRODUCTS, 2019, 130 :1-8

[7] Cardanol: A promising building block for biobased polymers and additives [J].

Caillol, Sylvain .

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2018, 14 :26-32

[8] mussel-inspired delivery system for enhancing self-healing property of epoxy coatings [J].

Cheng, Li ;

Liu, Chengbao ;

Wu, Hao ;

Zhao, Haichao ;

Mao, Feixiong ;

Wang, Liping .

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2021, 80 :36-49

[9] Chemical transformations in technical cashew nut shell liquid and isolated mixture of cardanols, evaluation of the antioxidant activity and thermal stability of the products for use in pure biodiesel [J].

Costa, Kenia de P. ;

de Viveiros, Barbara M. ;

Schmidt Junior, Marco Aurelio S. ;

Suarez, Paulo A. Z. ;

Rezende, Michelle J. C. .

FUEL, 2019, 235 :1010-1018

[10] Recent advances in the field of selective epoxidation of vegetable oils and their derivatives: a review and perspective [J].

Danov, S. M. ;

Kazantsev, O. A. ;

Esipovich, A. L. ;

Belousov, A. S. ;

Rogozhin, A. E. ;

Kanakov, E. A. .

CATALYSIS SCIENCE & TECHNOLOGY, 2017, 7 (17) :3659-3675

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