A gas phase analysis technique applied to in-situ studies of gas-solid interactions

被引：7

作者：

Anghel, Clara ^{[1
]}

Dong, Qian ^{[1
]}

机构：

[1] Royal Inst Technol, Dept Mat Sci & Engn, Div Corros Sci, S-10044 Stockholm, Sweden

来源：

JOURNAL OF MATERIALS SCIENCE | 2007年 / 42卷 / 10期

关键词：

D O I：

10.1007/s10853-006-1023-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

An ultrahigh vacuum technique using mass spectrometry for in-situ investigations of gas-solid interactions is described in this paper. Examples of chemical reactions (oxidation, hydration) between solids and gas mixtures, dissociation of gases on solid surfaces, outgassing of solid materials and permeation of gases through membranes are discussed where the experimental arrangement is explained in detail. This Gas Phase Analysis (GPA) technique can be used at temperatures from room temperature to 1200 degrees C and at pressures up to 1 atm. Aspects related to sample preparation, isotopic gas mixture selection, data acquisition, calibration and interpretation of the experimental data are also addressed.

引用

页码：3440 / 3453

页数：14

共 44 条

[1] Release of water and hydrogen during outgassing of some materials [J].

Akermark, T ;

Hultquist, G ;

Lu, Q .

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 1996, 5 (04) :516-520

[2] The use of oxygen isotopic labeling to understand oxidation mechanisms [J].

Akermark, T .

OXIDATION OF METALS, 1998, 50 (3-4) :167-188

[3]

Akermark TN, 1996, J TRACE MICROPROBE T, V14, P377

[4] Gas-tight oxides -: Reality or just a hope [J].

Anghel, C. ;

Hultquist, G. ;

Dong, Q. ;

Rundgren, J. ;

Saeki, I. ;

Limback, M. .

HIGH-TEMPERATURE OXIDATION AND CORROSION 2005, 2006, 522-523 :93-101

[5] Influence of Pt, Fe/Ni/Cr-containing intermetallics and deuterium on the oxidation of Zr-based materials [J].

Anghel, C ;

Hultquist, G ;

Limbäck, M .

JOURNAL OF NUCLEAR MATERIALS, 2005, 340 (2-3) :271-283

[6] Gas phase analysis of CO interactions with solid surfaces at high temperatures [J].

Anghel, C ;

Hörnlund, E ;

Hultquist, G ;

Limbäck, M .

APPLIED SURFACE SCIENCE, 2004, 233 (1-4) :392-401

[7]

ANGHEL C, 2004, THESIS ROYAL I TECHN

[8]

BARRER R, 1941, DIFFUSION IN THROUGH, P10

[9] RECOMMENDED PRACTICE FOR THE CALIBRATION OF MASS SPECTROMETERS FOR PARTIAL-PRESSURE ANALYSIS [J].

BASFORD, JA ;

BOECKMANN, MD ;

ELLEFSON, RE ;

FILIPPELLI, AR ;

HOLKEBOER, DH ;

LIESZKOVSZKY, L ;

STUPAK, CM .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1993, 11 (03) :A22-A40

[10] Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides [J].

Bassat, JM ;

Petitjean, M ;

Fouletier, J ;

Lalanne, C ;

Caboche, G ;

Mauvy, F ;

Grenier, JC .

APPLIED CATALYSIS A-GENERAL, 2005, 289 (01) :84-89

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