Easy synthesis of MnO-graphene hybrids for high-performance lithium storage

被引:13
作者
Gao Feng [1 ,2 ]
Qu Jiang-ying [1 ,2 ]
Zhao Zong-bin [1 ]
Dong Yan-feng [1 ]
Yang Juan [1 ]
Dong Qiang [1 ]
Qiu Jie-shan [1 ]
机构
[1] Dalian Univ Technol, Carbon Res Lab, Liaoning Key Lab Energy Mat & Chem Engn, Sch Chem Engn,State Key Lab Fine Chem, Dalian 116024, Peoples R China
[2] Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Lithium ion batteries; MnSO4/graphene oxide suspension; Graphene; MnO/graphene hybrid; CAPACITY ANODE MATERIAL; ELECTRODE MATERIALS; RAMAN-SPECTROSCOPY; MN3O4; NANOSHEETS; SHEETS;
D O I
10.1016/S1872-5805(14)60141-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Graphene oxide was produced using a modified Hummers method and used to produce a MnSO4-graphene oxide (MnSO4-GO) hybrid which was then transformed into a MnO-graphene hybrid by precipitation with NaOH followed by hydrogen reduction. The MnO-graphene hybrid shows a high specific capacity of 870 mAh.g(-1) at 100 mA.g(-1) as an anode material for lithium ion batteries, which is much higher than that of bare MnO (around 456 mAh.g(-1)). A capacity of 390 mAh.g(-1) could be maintained even at a high current density of 1 600 mA.g(-1). This green and highly efficient approach offers a new technique for the synthesis of MnOx-graphene battery materials.
引用
收藏
页码:316 / 321
页数:6
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