Bioenabled Platform to Access Polyamides with Built-In Target Properties

被引：14

作者：

Carter, Prerana ^{[1
]}

Trettin, James L. ^{[1
,2
]}

Lee, Ting-Han ^{[1
]}

Chalgren, Nickolas L. ^{[1
]}

Forrester, Michael J. ^{[1
]}

Shanks, Brent H. ^{[1
,2
]}

Tessonnier, Jean-Philippe ^{[1
,2
]}

Cochran, Eric W. ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem & Biol Engn, Ames, IA 50011 USA

[2] Ctr Biorenewable Chem CBiRC, Ames, IA 50011 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2022年 / 144卷 / 22期

基金：

美国国家科学基金会;

关键词：

ADIPIC ACID PRODUCTION; MUCONIC ACID; ISOMERIZATION; CONVERSION;

D O I：

10.1021/jacs.2c01397

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The diversification of platform chemicals is key to today's petroleum industry. Likewise, the flourishing of tomorrow's biorefineries will rely on molecules with next-generation properties from biomass. Herein, we explore this opportunity with a novel approach to monomers with custom property enhancements. Cyclic diacids with alkyl and aromatic decorations were synthesized from muconic acid by Diels-Alder cycloaddition, and copolymerized with hexamethylenediamine and adipic acid to yield polyamides with built-in hydrophobicity and flame retardancy. Testing shows a 70% reduction in water uptake and doubling of char production while largely retaining other key properties of the parent Nylon-6,6. The present approach can be generalized to access a wide range of performance-advantaged polyamides.

引用

页码：9548 / 9553

页数：6

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