Two facile synthesis routes for magnetic recoverable MnFe2O4/g-C3N4 nanocomposites to enhance visible light photo-Fenton activity for methylene blue degradation

被引:46
作者
Angkaew, Athaphon [1 ]
Chokejaroenrat, Chanat [1 ]
Sakulthaew, Chainarong [2 ]
Mao, Jin [3 ]
Watcharatharapong, Teeraphat [4 ]
Watcharenwong, Apichon [5 ,6 ]
Imman, Saksit [7 ]
Suriyachai, Nopparat [7 ]
Kreetachat, Torpong [7 ]
机构
[1] Kasetsart Univ, Fac Environm, Dept Environm Technol & Management, Bangkok 10900, Thailand
[2] Kasetsart Univ, Fac Vet Technol, Dept Vet Technol, Bangkok 10900, Thailand
[3] Chinese Acad Agr Sci, Oil Crops Res Inst, Natl Reference Lab Agr Testing PR China,Minist Ag, Key Lab Detect Mycotoxins,Lab Qual & Safety Risk, Wuhan 430062, Peoples R China
[4] Kasetsart Univ, Fac Sci, Dept Phys, Bangkok 10900, Thailand
[5] Suranaree Univ Technol, Sch Environm Engn, Inst Engn, Nakhon Ratchasima 30000, Thailand
[6] Suranaree Univ Technol, Ctr Excellence Adv Funct Mat, Nakhon Ratchasima 30000, Thailand
[7] Univ Phayao, Integrated Biorefinery Excellent Ctr IBC, Sch Energy & Environm, Phayao 56000, Thailand
来源
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING | 2021年 / 9卷 / 04期
关键词
Catalysis mechanism; Graphitic carbon nitrile; Heterogeneous photo-Fenton catalyst; Manganese ferrite; Magnetic nanocomposites; Singlet oxygen; ADVANCED OXIDATION PROCESSES; PEROXYMONOSULFATE ACTIVATION; HYDROGEN-PEROXIDE; MANGANESE FERRITE; OXYGEN VACANCIES; CATALYST; WATER; DECOMPOSITION; G-C3N4; OXIDE;
D O I
10.1016/j.jece.2021.105621
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
High-efficiency photocatalyst MnFe2O4/g-C3N4 nanocomposites were successfully synthesized to degrade methylene blue (MB). Two types of magnetic recoverable nanocomposite (MG1 and MG2), which were fabricated using co-precipitation and calcination methods, were characterized using various analytical techniques and applied as heterogeneous catalysts for H2O2 activation under simulated sunlight irradiation. The results revealed that composing g-C3N4 in the composites improved the MnFe2O4 crystallinity and increased the material magnetism which facilitated them for efficient recovery using an external magnet. The MG2 synthesis strategy effectively suppressed particle aggregation and immensely increased the active surface area more than for MG1. The quenching experiments revealed that photogenerated electrons played an important role in the catalytic reaction and singlet oxygen (O-1(2)) was a dominant reactive species for MB degradation. The XPS analysis before and after treatment confirmed that the generated O-1(2) was derived from the interaction of metal ions and oxygen vacancy in the H2O2 activation. While both nanocomposites exhibited excellent catalytic ability at near-neutral pH levels and for different real water matrices, MG2 had better MB degradation performance but greater difficulty with gravity settling due to its much smaller particle sizes. Therefore, MG2 large-scale production may require more cumbersome steps. However, both nanocomposites showed high crystallinity and very low metal leaching after several uses and still maintained their magnetism. These observations support the use of our MG nanocomposites as potential photocatalysts to activate H2O2 for the degradation of an organic contaminant in water.
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页数:14
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共 65 条
[1]   Degradation and mineralization of methylene blue using a heterogeneous photo-Fenton catalyst under visible and solar light irradiation [J].
Ahmed, Yunus ;
Yaakob, Zahira ;
Akhtar, Parul .
CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (04) :1222-1232
[2]   Decontamination of Aqueous Glyphosate, (Aminomethyl) phosphonic Acid, and Glufosinate Solutions by Electro-Fenton-like Process with Mn2+ as the Catalyst [J].
Balci, Beytul ;
Oturan, Mehmet A. ;
Oturan, Nihal ;
Sires, Ignasi .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2009, 57 (11) :4888-4894
[3]   Visible light-assisted heterogeneous Fenton with ZnFe2O4 for the degradation of Orange II in water [J].
Cai, Chun ;
Zhang, Zhuoyue ;
Liu, Jin ;
Shan, Ni ;
Zhang, Hui ;
Dionysiou, Dionysios D. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 182 :456-468
[4]   Photoinduced g-C3N4-promoted Mn2+/Mn3+/Mn4+ redox cycles for activation of peroxymonosulfate [J].
Chai, Chen ;
Fan, Caimei ;
Liu, Jianxin ;
Zhang, Xiaochao ;
Wang, Yawen ;
Li, Rui ;
Duan, Donghong ;
Wang, Yunfang .
JOURNAL OF SOLID STATE CHEMISTRY, 2019, 277 :466-474
[5]   Heterogeneous photo-Fenton reaction on hematite (α-Fe2O3){104}, {113} and {001} surface facets [J].
Chan, J. Y. T. ;
Ang, S. Y. ;
Ye, E. Y. ;
Sullivan, M. ;
Zhang, J. ;
Lin, M. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (38) :25333-25341
[6]   Chemical characteristics and acid drainage assessment of mine tailings from Akara Gold mine in Thailand [J].
Changul, Chulalak ;
Sutthirat, Chakkaphan ;
Padmanahban, G. ;
Tongcumpou, Chantra .
ENVIRONMENTAL EARTH SCIENCES, 2010, 60 (08) :1583-1595
[7]   Enhanced degradation of triclosan by cobalt manganese spinel-type oxide activated peroxymonosulfate oxidation process via sulfate radicals and singlet oxygen: Mechanisms and intermediates identification [J].
Chen, Zhiping ;
Bi, Sijing ;
Zhao, Guangyi ;
Chen, Yuancai ;
Hu, Yongyou .
SCIENCE OF THE TOTAL ENVIRONMENT, 2020, 711
[8]   Metal-free activation of H2O2 by g-C3N4 under visible light irradiation for the degradation of organic pollutants [J].
Cui, Yanjuan ;
Ding, Zhengxin ;
Liu, Ping ;
Antonietti, Markus ;
Fu, Xianzhi ;
Wang, Xinchen .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (04) :1455-1462
[9]   Removal of azo dye CI Acid Red 14 from contaminated water using fenton, UV/H2O2, UV/H2O2/Fe(II), UV/H2O2/Fe(III) and UV/H2O2/Fe(III)/oxalate processes:: A comparative study [J].
Daneshvar, N ;
Khataee, AR .
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2006, 41 (03) :315-328
[10]   Mn-doped g-C3N4 composite to activate peroxymonosulfate for acetaminophen degradation: The role of superoxide anion and singlet oxygen [J].
Fan, Jinhong ;
Qin, Hehe ;
Jiang, Simin .
CHEMICAL ENGINEERING JOURNAL, 2019, 359 :723-732