New chiral binaphthalene-derived iminium salt organocatalysts for asymmetric epoxidation of alkenes

被引：38
作者：
Page, Philip C. Bulman [1 ]
Farah, Mohamed M.
Buckley, Benjamin R.
Blacker, A. John
机构：
[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
[2] NPIL Pharmaceut UK Ltd, Huddersfield HD2 1GA, W Yorkshire, England
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 12期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1021/jo070255w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of binaphthalene-fused azepinium salts has been generated and used as organocatalysts in the asymmetric epoxidation of unfunctionalized alkenes, giving rise to ees of up to 84%.
引用
收藏
页码：4424 / 4430
页数：7
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