Palladium-catalyzed carbonylative coupling reactions using triorganoindium compounds

被引：0

作者：

Pena, MA ^{[1
]}

Sestelo, JP ^{[1
]}

Sarandeses, LA ^{[1
]}

机构：

[1] Univ A Coruna, Dept Quim Fundamental, La Coruna 15071, Spain

来源：

SYNTHESIS-STUTTGART | 2003年 / 05期

关键词：

atom economy; indium; carbonylative cross-coupling; organometallic reagents; palladium catalysis;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel palladium-catalyzed carbonylative cross-coupling reaction that employs triorganoindium compounds is described. The reaction proceeds under a carbon monoxide atmosphere with alkyl-, alkynyl-, and arylindium reagents to give good yields of unsymmetrical ketones with high atom economy. All three organic groups attached to the metal are efficiently transferred in this carbonylative coupling reaction.

引用

页码：780 / 784

页数：5

共 45 条

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