Three-photon Absorption and Optical Power Limiting of Triphenylamine-pyridine Derivatives

被引：0
作者：
Hu Kaiming [1 ]
Qian Ying [1 ]
Huang Wei [2 ]
Qi Qi [1 ]
Lue Changgui [2 ]
Sun Yueming [1 ]
Cui Yiping [2 ]
机构：
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
[2] Southeast Univ, Adv Photon Ctr, Nanjing 210096, Peoples R China
来源：
ACTA CHIMICA SINICA | 2010年 / 68卷 / 01期
关键词：
triphenylamine-pyridine derivative; three-photon absorption cross-section; three-photon fluorescence; single-photon fluorescence; optical power limiting; ORGANIC-COMPOUND; CROSS-SECTIONS; ENHANCEMENT; FLUORESCENCE; LASER; MICROFABRICATION; MICROSCOPY;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Triphenylamine-pyridine derivatives, 4-vinylpyridine-4'-(N,N-diphenylamino)benzene (PPAB), tris[4-(4-pyridylethenyl)phenyl]amine (TPPA), 4-(N,N-diphenylamine)benzene-vinyl-1-methyl-pyridinium iodide (PBPI), were synthesized and characterized. Single photon excited fluorescence and three-photon excited fluorescence of the chromophores were studied. When pumped with 1310 nm femtosecond laser irradiation, chromophores PPAB, PBPI and TPPA showed strong three-photon upconversion fluorescence at 648, 625, 696 nm, respectively. The chromophores displayed large three-photon absorption and strong optical power limiting properties. Their three-photon absorption coefficients obtained by a nonlinear transmission method using a femtosecond Ti:sapphire are 1.91 x 10(-79), 3.46 x 10(-79), and 3.64 x 10(-79) cm(6).s(2), respectively.
引用
收藏
页码：1 / 6
页数：6
相关论文
共 24 条
  • [1] Investigation of two-photon absorption properties in branched alkene and alkyne chromophores
    Bhaskar, Ajit
    Ramakrishna, Guda
    Lu, Zhikuan
    Twieg, Robert
    Hales, Joel M.
    Hagan, David J.
    Van Stryland, Eric
    Goodson, Theodore, III
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (36) : 11840 - 11849
  • [2] 3-PHOTON INDUCED UP-CONVERTED FLUORESCENCE FROM AN ORGANIC-COMPOUND - APPLICATION TO OPTICAL POWER LIMITING
    BHAWALKAR, JD
    HE, GS
    PRASAD, PN
    [J]. OPTICS COMMUNICATIONS, 1995, 119 (5-6) : 587 - 590
  • [3] Three-photon absorption enhancement in symmetrical charge transfer pull-pull fluorene derivatives
    Cohanoschi, I
    Belfield, KD
    Hernández, FE
    [J]. CHEMICAL PHYSICS LETTERS, 2005, 406 (4-6) : 462 - 466
  • [4] Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication
    Cumpston, BH
    Ananthavel, SP
    Barlow, S
    Dyer, DL
    Ehrlich, JE
    Erskine, LL
    Heikal, AA
    Kuebler, SM
    Lee, IYS
    McCord-Maughon, D
    Qin, JQ
    Röckel, H
    Rumi, M
    Wu, XL
    Marder, SR
    Perry, JW
    [J]. NATURE, 1999, 398 (6722) : 51 - 54
  • [5] 2-PHOTON LASER SCANNING FLUORESCENCE MICROSCOPY
    DENK, W
    STRICKLER, JH
    WEBB, WW
    [J]. SCIENCE, 1990, 248 (4951) : 73 - 76
  • [6] ACCESSING 3D MEMORY INFORMATION BY MEANS OF NONLINEAR ABSORPTION
    DVORNIKOV, AS
    RENTZEPIS, PM
    [J]. OPTICS COMMUNICATIONS, 1995, 119 (3-4) : 341 - 346
  • [7] Two-photon-enhanced three-photon absorption in transition-metal-doped semiconductor quantum dots
    Feng, X. B.
    Xing, G. C.
    Ji, W.
    [J]. JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS, 2009, 11 (02):
  • [8] 3-PHOTON-ABSORPTION-INDUCED FLUORESCENCE AND OPTICAL LIMITING EFFECTS IN AN ORGANIC-COMPOUND
    HE, GS
    BHAWALKAR, JD
    PRASAD, PN
    REINHARDT, BA
    [J]. OPTICS LETTERS, 1995, 20 (14) : 1524 - 1526
  • [9] Observation of stimulated emission by direct three-photon excitation
    He, GS
    Markowicz, PP
    Lin, TC
    Prasad, PN
    [J]. NATURE, 2002, 415 (6873) : 767 - 770
  • [10] Asymmetric properties between the forward and backward stimulated emission generated by ultrafast three- and four-photon excitation
    He, GS
    Lu, CG
    Zheng, QD
    Baev, A
    Samoc, M
    Prasad, PN
    [J]. PHYSICAL REVIEW A, 2006, 73 (03):
123