Preparation of Si/Sn-Based Nanoparticles Composited with Carbon Fibers and Improved Electrochemical Performance as Anode Materials

被引：30

作者：

Wang, Haiying ^{[1
]}

Huang, Hongqin ^{[1
]}

Chen, Lin ^{[1
]}

Wang, Chunguang ^{[1
]}

Yan, Bo ^{[1
]}

Yu, Yongtao ^{[2
]}

Yang, Yang ^{[1
]}

Yang, Gang ^{[1
]}

机构：

[1] Changshu Inst Technol, Dept Chem, Jiangsu Lab Adv Funct Mat, Changshu 215500, Peoples R China

[2] Petrochina Jilin, Petrochem Co Res Inst, Jilin 132021, Peoples R China

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2014年 / 2卷 / 10期

关键词：

Lithium ion batteries; Anode materials; Si/Sn@carbon; Composite materials; Electrospinning; NEGATIVE ELECTRODE; LITHIUM; LI; ALLOY; TIN; SILICON; NANOFIBERS; GRAPHITE; HETEROSTRUCTURES; MORPHOLOGY;

D O I：

10.1021/sc500290x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Si/Sn-based nanoparticles with various particle sizes are enwrapped in carbon nanofibers to improve the stability of Si/Sn during lithium alloying and dealloying. The composite structure of Si/Sn@carbon fibers is controllably synthesized by electrospinning and heat treatment. The crystal structure, content, and morphologies of Si/Sn@carbon composites are tunable by the carbonization conditions. The electrochemical performance of the composites is improved by the buffer effect of carbon fibers. The sample of SiSnC_800, which the precursor TEOS/SnCl2/PAN, is carbonized at 800 degrees C, delivers a specific capacity of 1347 mAh g(-1) at the second cycles, and retains 1073 mAh g(-1) at 50th cycle. The as-synthesized samples are flexible self-supporting films, which can be directly used as anode materials for lithium ion batteries.

引用

页码：2310 / 2317

页数：8

共 57 条

[1] Lithium insertion mechanism in Sb-based electrode materials from 121Sb Mossbauer spectrometry [J].

Aldon, L ;

Garcia, A ;

Olivier-Fourcade, J ;

Jumas, JC ;

Fernández-Madrigal, FJ ;

Lavela, P ;

Vicente, CP ;

Tirado, JL .

JOURNAL OF POWER SOURCES, 2003, 119 :585-590

[2] Electrospun nano-vanadium pentoxide cathode [J].

Ban, Chunmei ;

Chernova, Natalya A. ;

Whittingham, M. Stanley .

ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (03) :522-525

[3] The electrochemical reaction of Li with amorphous Si-Sn alloys [J].

Beaulieu, LY ;

Hewitt, KC ;

Turner, RL ;

Bonakdarpour, A ;

Abdo, AA ;

Christensen, L ;

Eberman, KW ;

Krause, JL ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (02) :A149-A156

[4] Colossal reversible volume changes in lithium alloys [J].

Beaulieu, LY ;

Eberman, KW ;

Turner, RL ;

Krause, LJ ;

Dahn, JR .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (09) :A137-A140

[5] Reaction of Li with alloy thin films studied by in situ AFM [J].

Beaulieu, LY ;

Hatchard, TD ;

Bonakdarpour, A ;

Fleischauer, MD ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (11) :A1457-A1464

[6] One dimensional Si/Sn - based nanowires and nanotubes for lithium-ion energy storage materials [J].

Choi, Nam-Soon ;

Yao, Yan ;

Cui, Yi ;

Cho, Jaephil .

JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (27) :9825-9840

[7] The impact of the addition of rare earth elements to Si1-xSnx negative electrode materials for Li-ion batteries [J].

Dahn, JR ;

Mar, RE ;

Fleischauer, MD ;

Obrovac, MN .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (06) :A1211-A1220

[8] An XPS study on the chemical bond structure at the interface between SiOxNy and N doped polyethylene terephthalate [J].

Ding, Wanyu ;

Li, Li ;

Zhang, Lina ;

Ju, Dongying ;

Peng, Shou ;

Chai, Weiping .

JOURNAL OF CHEMICAL PHYSICS, 2013, 138 (10)

[9] Challenges for Rechargeable Li Batteries [J].

Goodenough, John B. ;

Kim, Youngsik .

CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603

[10] Particle size effects on the electrochemical performance of copper oxides toward lithium [J].

Grugeon, S ;

Laruelle, S ;

Herrera-Urbina, R ;

Dupont, L ;

Poizot, P ;

Tarascon, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (04) :A285-A292

← 1 2 3 4 5 6 →