Iron-Catalyzed Synthesis of Sarmentine

被引:0
|
作者
Shakhmaev, R. N. [1 ]
Ignatishina, M. G. [1 ]
Zorin, V. V. [1 ]
机构
[1] Ufa State Petr Tech Univ, Ufa 450062, Russia
关键词
1-[(2E; 4E)-deca-2; 4-dienoyl]pyrrolidine; sarmentine; cross-coupling; iron catalysis; UNSATURATED AMIDE ALKALOIDS; STEREOSELECTIVE-SYNTHESIS; SEX-PHEROMONE; CHEMICAL-CONSTITUENTS; PIPER-LONGUM; COMPONENTS; ACETATE;
D O I
10.1134/S1070428021060178
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Stereoselective synthesis of sarmentine has been achieved via iron-catalyzed cross-coupling of pentylmagnesium bromide with ethyl (2E,4E)-5-chloropenta-2,4-dienoate obtained by one-pot oxidation-olefination of readily available (2E)-3-chloroprop-2-en-1-ol.
引用
收藏
页码:1002 / 1005
页数:4
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