Catalytic oxidation of alpha-carbon of ethers utilizing binuclear copper(II) complex of 7-azaindole

被引：19
作者：
Minakata, S
Imai, E
Ohshima, Y
Inaki, K
Ryu, I
Komatsu, M
Ohshiro, Y
机构：
[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN
[2] KINKI UNIV, SCI & TECHNOL RES INST, OSAKA 577, JAPAN
来源：
CHEMISTRY LETTERS | 1996年 / 01期
关键词：
D O I：
10.1246/cl.1996.19
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of benzyl ethyl ether with a catalytic amount of binuclear copper(II) complex of 7-azaindole 1 under oxygen atmosphere at 80 degrees C produced ethyl benzoate in 10400% yield based on the catalyst, This reaction could be also applied to other ethers (e.g., alkyl benzyl ethers and dialkyl ethers) to give alpha-oxygenated products catalytically.
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页码：19 / 20
页数：2
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